Home
Class 11
CHEMISTRY
At a certain temperature , K(p) for diss...

At a certain temperature , `K_(p)` for dissociation of solid `CaCO_(3)` is `4xx10^(-2)` atm and for the reaction, `C(s)+CO_(2) hArr 2CO` is `2.0` atm, respectively. Calculate the pressure of CO at this temperature when solid `C, CaO, CaCO_(3)` are mixed and allowed to attain equilibrium.

Text Solution

Verified by Experts

The correct Answer is:
A, B, C

For equation (i), `K_(p)=P_(CO_(2))`
from equation (ii), `K'_(p)=P_(CO)^(2)//P_(CO_(2))`
`:. K_(p)xxK'_(p)=(P_(CO))^(2)=4xx10^(-2)xx2=8xx10^(-2) "atm"^(2)`
`:. P_(CO)=sqrt(8xx10^(-2) "atm"^(2))=0.28 "atm"`
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL EQUILIBRIUM

    CENGAGE CHEMISTRY|Exercise Exercises (Subjective)|46 Videos
  • CHEMICAL EQUILIBRIUM

    CENGAGE CHEMISTRY|Exercise Exercises (Linked Comprehensive)|55 Videos
  • CHEMICAL EQUILIBRIUM

    CENGAGE CHEMISTRY|Exercise Concept Applicationexercise 7.1|53 Videos
  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    CENGAGE CHEMISTRY|Exercise Archives Subjective|15 Videos
  • CLASSIFICATION AND NOMENCLATURE OF ORGANIC COMPOUNDS

    CENGAGE CHEMISTRY|Exercise Analytical and Descriptive Type|3 Videos

Similar Questions

Explore conceptually related problems

For the reaction : CaCO_(3) (s) hArr CaO (s) + CO_(2) (g)

At 100 k , the pressure of CO_2 in equilibrium with CaCO_3 and CaO is equal to 3.9 xx 10^(-2) atm. The equilibrium constant for the reaction C(s) +CO_2 hArr 2CO(g) , is 1.9 at the same temperature when pressure are in atmospheres, solid carbon CaO and CaCO_3 are instead allowed to come to equilibrium at 100 K in closed vessel . what is the pressure of CO at equilibrium ?

Consider the heterogeneous equilibrium CaCO_3(s) hArr CaO(s) +CO_2(g) k_p=4 xx 10^(-2) atm ……….(i) C(s) +CO_2(g) hArr 2CO(g) K_p=2.0 atm ………(ii) Calculate the partial pressure of CO(g) when CaCO_3 and C are mixed and allowed to attain equilibrium at the temperature for which the above two equilibria have been studied.

For the reaction CaCO_(3(s)) hArr CaO_((s))+CO_(2(g))k_p is equal to

The reaction CaCO_(3) to CaO + CO_(2) is a _______ reaction .

Write the expression K_p for the reaction : CaCO_3(s) hArr CaO(s) +CO_2(g)

In the reaction C(s)+CO_(2)(g) hArr 2CO(g) , the equilibrium pressure is 12 atm. If 50% of CO_(2) reacts, calculate K_(p) .

CENGAGE CHEMISTRY-CHEMICAL EQUILIBRIUM-Ex 7.2
  1. The pressure of iodine gas at 1273 K is found to be 0.112 atm whereas ...

    Text Solution

    |

  2. K(c) for N(2)O(4)(g) hArr 2NO(2)(g) is 0.00466 at 298 K. If a 1-L cont...

    Text Solution

    |

  3. At a certain temperature , K(p) for dissociation of solid CaCO(3) is 4...

    Text Solution

    |

  4. Given below are the values of DeltaH^(ɵ) and DeltaS^(ɵ) for the reacti...

    Text Solution

    |

  5. The yield of product in the reaction, A(2)(g)+2B(g) hArr C(g)+Q KJ ...

    Text Solution

    |

  6. Manufacture of ammonia from the elements is represented by N(2)(g)+3...

    Text Solution

    |

  7. In the reaction, 2SO(2)(s)+O(2)(g) hArr 2SO(3)(g)+X cal, most favourab...

    Text Solution

    |

  8. In which of the following equilibrium, change in the volume of the sys...

    Text Solution

    |

  9. In the dissociation of 2HI hArr H(2)+I(2), the degree of dissociation ...

    Text Solution

    |

  10. In line kilns, the following reaction, CaCO(3)(s) hArr CaO(s)+CO(2)(...

    Text Solution

    |

  11. Which of the following reaction will be favoured at low pressure?

    Text Solution

    |

  12. If E(f) and E(r) are the activation energies of forward and backward r...

    Text Solution

    |

  13. K(p) for a reaction at 25^(@)C is 10 atm. The activation energy for fo...

    Text Solution

    |

  14. Concentration of pure solid and liquid is not included in the expressi...

    Text Solution

    |

  15. For an equilibrium reaction involving gases, the forward reaction is f...

    Text Solution

    |

  16. For the reaction, PCl(3)(g)+Cl(2)(g) hArr PCl(5)(g), the position of e...

    Text Solution

    |

  17. High pressure and low temperature are favourable conditions for the sy...

    Text Solution

    |

  18. Which of the following change will shift the reaction in forward direc...

    Text Solution

    |

  19. In a vessel containing SO(3), SO(2) and O(2) at equilibrium, some heli...

    Text Solution

    |

  20. Vapour density of the equilibrium mixture of NO(2) and N(2)O(4) is fou...

    Text Solution

    |