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The relation between K(p) and K(c) is K(...

The relation between `K_(p)` and `K_(c)` is `K_(p)=K_(c)(RT)^(Deltan)` unit of `K_(p)=(atm)^(Deltan)`, unit of `K_(c)=(mol L^(-1))^(Deltan)`
The equilibrium constant of the following reactions at `400 K` are given:
`2H_(2)O(g) hArr 2H_(2)(g)+O_(2)(g), K_(1)=3.0xx10^(-13)`
`2CO_(2)(g) hArr 2CO(g)+O_(2)(g), K_(2)=2xx10^(-12)`
Then, the equilibrium constant K for the reaction
`H_(2)(g)+CO_(2)(g) hArr CO(g)+H_(2)O(g)`
is

A

`2.04`

B

`20.5`

C

`0.85`

D

`1.4`

Text Solution

Verified by Experts

The correct Answer is:
D

From reaction (i) and (ii), we get
`2H_(2)(g)+2CO_(2)(g) hArr 2CO(g)+2H_(2)O(g),`
`K=1.7xx10^(-12)`
And hence `H_(2)+CO_(2) hArr CO+H_(2)O,`
`K=(1.7xx10^(-12))/(2)=0.85xx10^(-12)`
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