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K(1) and K(2) are equilibrium constants ...

`K_(1)` and `K_(2)` are equilibrium constants for reaction (i) and (ii)
`N_(2)(g)+O_(2)(g) hArr 2NO(g)` …(i)
`NO(g) hArr 1//2 N_(2)(g)+1//2O_(2)(g)` …(ii)
then,

A

`K_(1)=(1//K_(2))^(2)`

B

`K_(1)=K_(2)^(2)`

C

`K_(1)=1//K_(2)`

D

`K_(1)=(K_(2))^(@)`

Text Solution

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The correct Answer is:
To find the relationship between the equilibrium constants \( K_1 \) and \( K_2 \) for the given reactions, we will analyze each reaction step by step. ### Step 1: Write the Equations and Their Equilibrium Constants 1. The first reaction is: \[ N_2(g) + O_2(g) \rightleftharpoons 2NO(g) \] The equilibrium constant for this reaction is denoted as \( K_1 \). 2. The second reaction is: \[ NO(g) \rightleftharpoons \frac{1}{2} N_2(g) + \frac{1}{2} O_2(g) \] The equilibrium constant for this reaction is denoted as \( K_2 \). ### Step 2: Relate the Two Reactions The second reaction can be seen as the reverse of the first reaction, with stoichiometric coefficients halved. To relate \( K_1 \) and \( K_2 \), we need to consider the following: - When a reaction is reversed, the equilibrium constant for the reverse reaction is the reciprocal of the original equilibrium constant. Therefore, if we reverse the first reaction, we have: \[ 2NO(g) \rightleftharpoons N_2(g) + O_2(g) \] The equilibrium constant for this reversed reaction is: \[ K' = \frac{1}{K_1} \] ### Step 3: Adjust for Stoichiometry Since the second reaction is half of the reversed first reaction, we need to take the square root of the equilibrium constant: - When the coefficients of a balanced equation are multiplied by a factor, the equilibrium constant is raised to the power of that factor. In this case, since we are halving the coefficients, we take the square root: \[ K_2 = \sqrt{K'} \] Substituting \( K' \): \[ K_2 = \sqrt{\frac{1}{K_1}} = \frac{1}{\sqrt{K_1}} \] ### Step 4: Final Relationship Thus, we can express the relationship between \( K_1 \) and \( K_2 \) as: \[ K_2 = \frac{1}{\sqrt{K_1}} \] ### Step 5: Rewriting the Equation To express \( K_1 \) in terms of \( K_2 \): \[ K_1 = \frac{1}{K_2^2} \] ### Conclusion The final relationship between the equilibrium constants is: \[ K_1 = \frac{1}{K_2^2} \]

To find the relationship between the equilibrium constants \( K_1 \) and \( K_2 \) for the given reactions, we will analyze each reaction step by step. ### Step 1: Write the Equations and Their Equilibrium Constants 1. The first reaction is: \[ N_2(g) + O_2(g) \rightleftharpoons 2NO(g) \] The equilibrium constant for this reaction is denoted as \( K_1 \). ...
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