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Addition of inert gas to system at equil...

Addition of inert gas to system at equilibrium changes only `K_(p)` not `K_(c)`.

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Addition of inert gas to system N_(2)(g) + 3H_(2)(g) at equillibrium at constant volume. Then

Assertion (A) : Addition of an inert gas to the equilibrium mixture has no effect on the state of equilibrium at constant volume or at constant pressure. Reason (R ) : The addition of inert gas at constant volume will not alter the concentrations of the reactants as well as products of a reaction mixture.

Assertion :- Addition of inert gas at const pressure to equilibrium of PCl_(5)hArrPCl_(3)+Cl_(2) favourd forward reaction. Reason :- K_(c)=(alpha^(2))/((1-prop)V) for the equilibrium of PCl_(5)hArrPCl_(3)+Cl_(2)

Addition of an inert gas at constant volume to the equilibrium mixture does not affect the position of equilibrium.

Influence of pressure, temperature, concentration and addition of inert gas on a reversible chemical reaction in equilibrium can be explained by formulating the expression for equilibrium constant K_(c) or K_(p) for the equilibrium. On the other hand Le Chatelier principle can be theoretically used to explain the effect of P , T or concentration on the physical or chemical equilibrium both. N_(2)O_(4) is 66% dissociated into NO_(2) at 340K and 1 atmospheric pressure. The volume occupied by 10gN_(2)O_(4) under these conditions is:

Influence of pressure, temperature, concentration and addition of inert gas on a reversible chemical reaction in equilibrium can be explained by formulating the expression for equilibrium constant K_(c) or K_(p) for the equilibrium. On the other hand Le Chatelier principle can be theoretically used to explain the effect of P , T or concentration on the physical or chemical equilibrium both. n moles of a reactant A gives one mole of B and C . If degree of dissociation of A is independent of initial concentration of A , then n is:

Influence of pressure, temperature, concentration and addition of inert gas on a reversible chemical reaction in equilibrium can be explained by formulating the expression for equilibrium constant K_(c) or K_(p) for the equilibrium. On the other hand Le Chatelier principle can be theoretically used to explain the effect of P , T or concentration on the physical or chemical equilibrium both. For the reaction: underset(Yellow)(Fe_((aq.))^(3+))+SCN_((aq.))^(-)hArrunderset(Red)([Fe(NCS)]_((aq.))^(2+)) in equilibrium if little more aqueous solution in FeCl_(3) is added, then:

Influence of pressure, temperature, concentration and addition of inert gas on a reversible chemical reaction in equilibrium can be explained by formulating the expression for equilibrium constant K_(c) or K_(p) for the equilibrium. On the other hand Le Chatelier principle can be theoretically used to explain the effect of P , T or concentration on the physical or chemical equilibrium both. For the reaction : PCl_(5)hArrPCl_(3)+Cl_(2) , increase of pressure shows.

CENGAGE CHEMISTRY-CHEMICAL EQUILIBRIUM-Exercises (True/False)
  1. The dissociation of CaCO(3) is suppressed at high pressure

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  2. More of SO(3) decompose at loe temperature.

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  3. Addition of inert gas to system at equilibrium changes only K(p) not K...

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  4. The melting of ice in water decreases with increase in pressure.

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  5. The evaporation of liquid with increase in pressure.

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  6. If equilibrium constant for the reaction A(2)+B(2) hArr 2AB is k, th...

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  7. K(p) is equal to K(c) if Deltan is positive.

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  8. The value K(c) of a reaction has a higher value at higher temperature....

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  9. The reaction having higher value of equilibrium constant is faster tha...

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  10. Ammonium chloride dissociates as, NH(4)Cl(g) hArr NH(3)(g)+HCl(g) ...

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  11. The low of mass action applicable to heterogenous equilibria.

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  12. Equilibrium can be achieved only in open vessel.

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  13. The solubility of sodium hydroxide increases with increase of temperat...

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  14. The degree of dissociation of PCl(5) decreases with increase in pressu...

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  15. High pressure and low temperature are favourable conditions for the sy...

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  16. An endothermic reaction proceeds faster in the forward reaction with d...

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  17. A catalyst increases the rate of forward reaction and decrease the rat...

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  18. The value of K does not depends upon pressure.

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  19. For any reaction, greater the value of equilibrium constant greater is...

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  20. Solid hArr liquid equilibrium can be achieved only at melting point of...

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