Home
Class 11
CHEMISTRY
What mass of pb^(2+) ions is left in sol...

What mass of `pb^(2+)` ions is left in solution, when `50.0mL` of `0.20M Pb(NO_(3))_(2)` is added to `50.0mL` of `1.5M NAC1`?

Text Solution

Verified by Experts

Assume complete precipitation of the `Pb^(2+)` followed by solution of the equilibrium concentration to be determined.
`(50.0mL) (0.20M) = 10 mmol Pb^(2+)`
`(50.0mL) (1.5M) = 75 mmol C1^(Θ)`
`Pb^(2+) + 2C1^(Θ) hArrPbC1_(2)`
When lead ion concentration can exist in a solution of `C1^(Θ)` containing `(75mmol) -(20 mmol) = 55 mmol` in `100mL? [C1^(Θ)] = 0.55M`
`PbC1_(2) hArr Pb^(2+) + 2C1^(Θ)`
`K_(sp) [Pb^(2+)] [C1^(2+)] [C1^(Θ)]^(2) = 1.7 xx 10^(-4)`
`[Pb^(2+)] = (1.7 xx 10^(-4))/((0.55)^(2)) = 5.6 xx 10^(-4)M`
`(5.6 xx 10^(-4) mol L^(-1) (0.100L) (208 g mol^(-1)) = 12 mg`
Promotional Banner

Topper's Solved these Questions

  • IONIC EQUILIBRIUM

    CENGAGE CHEMISTRY|Exercise Ex 8.1|18 Videos
  • IONIC EQUILIBRIUM

    CENGAGE CHEMISTRY|Exercise Ex 8.2|27 Videos
  • HYDROGEN, WATER AND HYDROGEN PEROXIDE

    CENGAGE CHEMISTRY|Exercise Subjective Archive (Subjective)|3 Videos
  • ISOMERISM

    CENGAGE CHEMISTRY|Exercise Assertion-Reasoning Type|1 Videos

Similar Questions

Explore conceptually related problems

K_(sp) of PbC1_(2) is 10^(-13) . What will be [Pb^(2+)] in a of solution prepared by mixing 100mL of 0.1MPb(NO_(3))_(2) of solution 1.0mL 1M HCI ?

What is the maximum mass of PbI_(2) that can be precipitated by mixing 25.0 mL of 0.100 M Pb(NO_(3))_(2) with 35.0 mL of 0.100 M NaI?

Calculate the pH of resulting solution, when 50 mL of 0.20M HCI is mixed with 50 mL of 0.20M CH_(3)COOH .

Which of the following will be present in the soluiton formed when 50mL of 0.1 M HCl is mixed with 50mL of 0.1 M NaOH ?

What are the final concentrations of all the ions when following are mixed? 50 mL of 0.12M Fe(NO_(3))_(3), 100 mL of 0.10M FeCl_(3) and 100mL of 0.26M Mg(NO_(3))_(2)

Calclate pH of a resultant solution of 25 mL of 0.1 M HCl, 50 mL of 0.02 M HNO_(3) and 25 mL of 0.1M NaOH

The nature of mixture obtained by mixing 50mL of 0.1M H_(2)SO_(4) and 50mL of 0.1M NaOh is:

The K_(sp) for the following dissociation is 2.2 xx 10^(-2) PbCl_(2(s)) f ""Pb_((aq))^(2+)+2Cl_((aq))^(-) Which of the following choices is correct for a mixture of 350mL 0.225M Pb(NO_(3))_(2) and 200 mL 0.6 M NaCl ?

CENGAGE CHEMISTRY-IONIC EQUILIBRIUM-Archives Subjective
  1. What mass of pb^(2+) ions is left in solution, when 50.0mL of 0.20M Pb...

    Text Solution

    |

  2. How much moles of sodium propionate should be added to 1L of an aqueou...

    Text Solution

    |

  3. Given reason for the statement that the pH of an aqueous solution of s...

    Text Solution

    |

  4. 20 mL of 0.2M sodium hydroxide is added to 50 mL of 0.2 M acetic acid ...

    Text Solution

    |

  5. The dissociation constant of a weak acid HA si 4.9 xx 10^(-8). After m...

    Text Solution

    |

  6. A solution contains a mixture of Ag^(+)(0.10M) and Hg(2)^(2+)(0.10M) w...

    Text Solution

    |

  7. The concentration of hydrogen ions in a 0.2M solution of formic acid i...

    Text Solution

    |

  8. The solubility of Mg (OH)(2) in pure water is 9.57 xx 10^(-3) gL^(-1)....

    Text Solution

    |

  9. What is the pH of the solution when 0.20 mol of HCI is added to 1L of ...

    Text Solution

    |

  10. How many gram moles of HCI will be required to prepare 1L of buffer so...

    Text Solution

    |

  11. Freshly precipiteated Al and Mg hydroxides are stirred vigorously in a...

    Text Solution

    |

  12. What is the pH of 1 M solution of acetic acid ? To what volume one lit...

    Text Solution

    |

  13. A 50 mL solution of weak base BOH is titrated with 0.1N HCI solution. ...

    Text Solution

    |

  14. The K(SP) of Ag(2)C(2)O(4) at 25^(@)C is 1.29xx10^(-11)mol^(3)L^(-3). ...

    Text Solution

    |

  15. The K(SP)of Ca(OH)(2)is 4.42xx10^(-5)at 25^(@)C. A 500 mL of saturated...

    Text Solution

    |

  16. The pH of blood stream is maintained by a proper balance of H(2)CO(3) ...

    Text Solution

    |

  17. An aqueous solution of a metal bromide MBr(2)(0.05M) is saturated with...

    Text Solution

    |

  18. For the reaction Ag(CN)(2)^(ɵ)hArr Ag^(o+)+2CN^(ɵ), the K(c ) at 25^...

    Text Solution

    |

  19. Calculate the pH of an aqueous solution of 1.0M ammonium formate assum...

    Text Solution

    |

  20. What is the pH of a 0.50M aqueous NaCN solution ? (pK(b)of CN^(-)=4.70...

    Text Solution

    |

  21. The ionization constant of overset(o+)(NH(4)) ion in water is 5.6 xx 1...

    Text Solution

    |