Home
Class 11
CHEMISTRY
2H(2)O hArr H(3)O^(o+) + overset(Theta)O...

`2H_(2)O hArr H_(3)O^(o+) + overset(Theta)OH,K_(w) = 10^(-14)` at `25^(@)C`, hence `K_(a)` is

A

`10^(-7)`

B

`5.55 xx 10^(-13)`

C

`10^(-14)`

D

`18 xx 10^(-17)`

Text Solution

Verified by Experts

The correct Answer is:
D

`K_(a) = ([H^(o+)][overset(Theta)OH])/([H_(2)O]) = (K_(w))/([H_(2)O]) = (10^(-14))/(55.6) = 18 xx 10^(-17)`
`(M` of `H_(2)O = 55.6)`
Promotional Banner

Topper's Solved these Questions

  • IONIC EQUILIBRIUM

    CENGAGE CHEMISTRY|Exercise Ex 8.3|38 Videos
  • IONIC EQUILIBRIUM

    CENGAGE CHEMISTRY|Exercise Ex 8.4|39 Videos
  • IONIC EQUILIBRIUM

    CENGAGE CHEMISTRY|Exercise Ex 8.1|18 Videos
  • HYDROGEN, WATER AND HYDROGEN PEROXIDE

    CENGAGE CHEMISTRY|Exercise Subjective Archive (Subjective)|3 Videos
  • ISOMERISM

    CENGAGE CHEMISTRY|Exercise Assertion-Reasoning Type|1 Videos

Similar Questions

Explore conceptually related problems

2H_(2)OhArrH_(3)O^(+)+OH^(-) K_(w)=1xx10^(-14) at 25^(@)C . Hence, K_(a) is:

Calculate the dissociation constant of NH_(4)OH at 298k , if DeltaH^(Theta) and DeltaS^(Theta) for the given changes are as follows:- NH_(3) + H^(o+) hArr overset(o+)NH_(4) , DeltaH^(Theta) =- 52.2 KJ mol^(-1), DeltaS^(Theta) = 1.67 J K^(-1)mol^(-1) H_(2)O hArr H^(o+) + overset(Theta)OH, DeltaH^(Theta) = 56.6 kJ mol^(-1) . DeltaS^(Theta) =- 76.53 JK^(-1)mol^(-1)

The K_(w) for 2H_(2)O hArr H_(3)O^(+)_OH^(-) changes from 10^(-14) at 25^(@)C to 9.62xx10^(-14) at 60^(@)C . What is pH of water at 60^(@)C ? What happens to its neutrality ?

Calculate the [overset(Theta)OH] of [NH_(2)C_(2)H_(4)NH_(3)]^(o+) and [H_(3)N-C_(2)H_(4)NH_(3)]^(2+) in 0.15M ethylene diamine (aq) if NH_(2)C_(2)H_(4)NH_(2)+H_(2)O hArr NH_(2)C_(2)H_(4)overset(o+)NH_(3)+overset(Theta)OH (K_(1) = 8.5 xx 10^(-5)) NH_(2)C_(2)H_(4)overset(o+)NH_(3) +H_(2)O hArr [NH_(3)C_(2)H_(4)NH_(3)]^(2+) + overset(Theta)OH (K_(2) = 2.7 xx 10^(-8))

In atmosphere, SO_(2) and NO are oxidised to SO_(3) and NO_(2) , respectively,w hcih react with water to given H_(2)SO_(4) and HNO_(3) . The resultant solution is called acid rain. SO_(2) dissolves in water to form diprotic acid. SO_(2)(g) +H_(2)O(l) hArr HSO_(3)^(Theta) + H^(o+), K_(a_(1)) = 10^(-2) . HSO_(3)^(Theta) hArr SO_(3)^(2-) + H^(o+), K_(a_(2)) = 10^(-7) and for equilibrium, SO_(2)(aq) + H_(2)O (l) hArr SO_(3)^(2-)(aq) +2H^(o+)(aq) K_(a) = K_(a_(1)) xx K_(a_(2)) = 10^(-9) at 300K . The pH of 0.01M aqueous solutioon of sodium sulphite (Na_(2)SO_(3))

In atmosphere, SO_(2) and NO are oxidised to SO_(3) and NO_(2) , respectively,w hcih react with water to given H_(2)SO_(4) and HNO_(3) . The resultant solution is called acid rain. SO_(2) dissolves in water to form diprotic acid. SO_(2)(g) +H_(2)O(l) hArr HSO_(3)^(Theta) + H^(o+), K_(a_(1)) = 10^(-2) . HSO_(3)^(Theta) hArr SO_(3)^(2-) + H^(o+), K_(a_(2)) = 10^(-7) and for equilibrium, SO_(2)(aq) + H_(2)O (l) hArr SO_(3)^(2-)(aq) +2H^(o+)(aq) K_(a) = K_(a_(1)) xx K_(a_(2)) = 10^(-9) at 300K . Which of the following statement is correct?

In atmosphere, SO_(2) and NO are oxidised to SO_(3) and NO_(2) , respectively,w hcih react with water to given H_(2)SO_(4) and HNO_(3) . The resultant solution is called acid rain. SO_(2) dissolves in water to form diprotic acid. SO_(2)(g) +H_(2)O(l) hArr HSO_(3)^(Theta) + H^(o+), K_(a_(1)) = 10^(-2) . HSO_(3)^(Theta) hArr SO_(3)^(2-) + H^(o+), K_(a_(2)) = 10^(-7) and for equilibrium, SO_(2)(aq) + H_(2)O (l) hArr SO_(3)^(2-)(aq) +2H^(o+)(aq) K_(a) = K_(a_(1)) xx K_(a_(2)) = 10^(-9) at 300K . Which of the following reagnets will given white precipitate with the aqueous solution of sulphurous acid?

If the equilibrium constant of BOH harr B^(o+) +overset(Theta)OH at 25^(@)C is 2.5 xx 10^(-6) , then equilibrium constant for BOH +H^(o+) hArr B^(o+)+H_(2)O at the same temperature is

Calculate the entropy of overset(Θ)OH ion at 298K . Given: a. H_(2)O hArr H^(o+) + overset(Θ)OH (DeltaH = 13.4 kcal) b. K_(eq) for the reaction = 10^(-14) . c. S^(Θ) (H^(o+)) = 0.0 d. S^(Θ) (H_(2)O) = 16.7 cal//mol k .

CENGAGE CHEMISTRY-IONIC EQUILIBRIUM-Ex 8.2
  1. At 90^(@)C, pure water has [H(3)O^(o+)] = 10^(-6)M. What is the value ...

    Text Solution

    |

  2. HCOOH and CH(3)COOH solutions have equal pH. If K(1)//K(2) is 4, the r...

    Text Solution

    |

  3. 2H(2)O hArr H(3)O^(o+) + overset(Theta)OH,K(w) = 10^(-14) at 25^(@)C, ...

    Text Solution

    |

  4. Which of the following expression is wrong?

    Text Solution

    |

  5. For a 'C'M concentarted solution of a weak electrolyte A(x)B(y)alpha(d...

    Text Solution

    |

  6. K(b) for NH(4)OH is 1.8 xx 10^(-5). The [overset(Theta)OH] of 0.1 M NH...

    Text Solution

    |

  7. The dissociation constant of monobasic acids A, B,C and D are 6 xx 10^...

    Text Solution

    |

  8. The molarity of NH(3) of pH = 12 at 25^(@)C is (K(b) = 1.8 xx 10^(-5))

    Text Solution

    |

  9. K(a) of HA at 25^(@) is 10^(-5). If 0.1mol of this acid is dissolved i...

    Text Solution

    |

  10. For a polyprotic acid, H(3)PO(4) its three dissociation constanst K(1)...

    Text Solution

    |

  11. Given HF + H(@)O overset(K(g))hArr H(3)O^(o+) + f^(o+) F^(Theta) + H...

    Text Solution

    |

  12. A certain weak acid has a dissociation constant 1.0xx10^(-4). The equi...

    Text Solution

    |

  13. The percentage error in [H^(o+)] provided by 10^(-8)M HC1, if ionisati...

    Text Solution

    |

  14. H(3)BO(3) is :

    Text Solution

    |

  15. The enthalpy change for first proton neutralisation of H(2)S is -37.1k...

    Text Solution

    |

  16. The factor by which the degree of ionisation of 200mL of 0.1M benzoic ...

    Text Solution

    |

  17. The concentration of CO(2) in atmosphere is 88ppm. If all of the CO(2)...

    Text Solution

    |

  18. A solution of a weak monoprotic acid has dissociation constant K(a). T...

    Text Solution

    |

  19. Two weak acids HX and HY have K(a) values 1.75 xx 10^(-5) and 1.3 xx 1...

    Text Solution

    |

  20. H(2)S behaves as a weak diprotic acid in aqueous solution. Which of th...

    Text Solution

    |