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What would be the solubility of silver c...

What would be the solubility of silver chloride in `0.10M NaCI` solution?
`K_(sp) for AgCI = 1.20 xx 10^(-10)`

A

`0.1M`

B

`1.2 xx 10^(-6)M`

C

`1.2 xx 10^(-9)M`

D

`1.2 xx 10^(-10)M`

Text Solution

Verified by Experts

The correct Answer is:
C

`{:(AgCIhArr,Ag^(o+)+,CI^(Theta),,),(,x,x,,):}`
`{:(,NaCIrarr,Na^(o+)+,CI^(Theta),),("Initial",0.1,0,0,),("Final",0,0.1,0.1,):}`
`(NaCI` is salt of `S_(A)//S_(B)`. Which is completely ionised).
`:. CI^(Theta) = (x +0.1) ~~ 0.1` (Since `x` is very small)
`:. K_(sp) = [Ag^(o+)] [CI^(Theta)]`
`1.2 xx 10^(-10) = x xx0.1`
`x = (1.2 xx 10^(-10))/(0.1) = 1.2 xx 10^(-9)M`
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