Home
Class 11
CHEMISTRY
Show that the circumference of the Bohr ...

Show that the circumference of the Bohr orbit for the hydrogen atom is an integral multiple of the de Broglie wavelength associated with the electron revolving around the orbit.

Text Solution

Verified by Experts

According to de Broglie equation
`lambda=h/("mu")`
de-Broglie point out such closed orbits can exist only when the circumference of orbit equals to an integral multiple of the wavelength of electron as shown in figure.
i.e. , `2pir=nlambda`

Subtitute `lambda` from de Broglie equation
`2pir=nh/("mu")` or `"mur"=nh/(2pi)`
i.e., angular momentum is quantised for closed orbits. There is a stationary wave system for the de-Broglie waves for an electron in that orbit and the orbit must contain a whole number of electron waves as shown in figure. Clearly indicates `3` waves in third obit, `6` waves in sixths orbit and so on.
Promotional Banner

Topper's Solved these Questions

  • NCERT BASED EXERCISE

    CENGAGE CHEMISTRY|Exercise Thermodynamics|50 Videos
  • NCERT BASED EXERCISE

    CENGAGE CHEMISTRY|Exercise Chemical Equilibrium|72 Videos
  • NCERT BASED EXERCISE

    CENGAGE CHEMISTRY|Exercise Redox Reaction|25 Videos
  • ISOMERISM

    CENGAGE CHEMISTRY|Exercise Assertion-Reasoning Type|1 Videos
  • ORGANIC REACTION MECHANISM

    CENGAGE CHEMISTRY|Exercise Analytical and Descriptive|6 Videos

Similar Questions

Explore conceptually related problems

What is the de-Broglie wavelength associated with the hydrogen electron in its third orbit

The De Broglie wavelenght associated with electron in n Bohr orbit is

The de-Broglie wavelength of an electron revolving in the ground state orbit is

State the expression for the radius of the nth Bohr orbit in a hydrogen atom. Hence state the expression for the de Broglie wavelength associated with the electron in this orbit.

Determine the de-Broglie wavelength associated with an electron in the 3rd Bohr's orbit of He^+ ion.

The circumference of circular orbit of electron in a He^(+) ion is five times the de-Broglie wavelength associated with the electron. Find the radius of the orbit.

The radius of the second orbit of an electron in hydrogen atom is 2.116A . The de Broglie wavelength associated with this electron in this orbit would be

The circumference of the second orbit of an atom or ion having single electron is 4 nm the de Broglie wavelength of electron (in nm) revolving in this orbit si :

CENGAGE CHEMISTRY-NCERT BASED EXERCISE-Atomic Structure
  1. Explain , giving reason , which of the following sets of quantum numbe...

    Text Solution

    |

  2. How many electron in an atom may have the following quantum number ? ...

    Text Solution

    |

  3. Show that the circumference of the Bohr orbit for the hydrogen atom is...

    Text Solution

    |

  4. What transition in the hydrogen spectrum would have the same wavelen...

    Text Solution

    |

  5. Calcultte the enrgy required for the process , He^+ (g) rarr He^(2+...

    Text Solution

    |

  6. If the diameter of a carbon atom is 0.15 nm, calculate the number of c...

    Text Solution

    |

  7. 2xx10^(8) atoms of carbon are arranged side by side. Calculate the rad...

    Text Solution

    |

  8. The diameyer of zinc atom is 2.6 A. Calculate (a) radius of zinc atom ...

    Text Solution

    |

  9. A certain particle carries 2.5xx10^(-16) C of static electric charge. ...

    Text Solution

    |

  10. In Milikan's experiment, static electrons charge on the oil drops has ...

    Text Solution

    |

  11. In Rutherford's experiment, generally the thin foil of heavy atoms, su...

    Text Solution

    |

  12. Symbols .(35)^(79)Br and .^(79)Br can be written, whereas symbols .(79...

    Text Solution

    |

  13. An element with mass number 81 contains 31.7% more neutrons as compare...

    Text Solution

    |

  14. An ion with mass number 37 possesses one unit off negative charge. If ...

    Text Solution

    |

  15. An ion with mass number 56 contains 3 units of positive charge and 30....

    Text Solution

    |

  16. Arrange the following type of radiations in increasing order of freque...

    Text Solution

    |

  17. Nitrogen laser produces a radiation at a wavelength of 33.71 nm. If th...

    Text Solution

    |

  18. Neon gas is generally used in the sign boards. If it emits strongly at...

    Text Solution

    |

  19. In astronomical observations, signals observed from the distant stars ...

    Text Solution

    |

  20. Lifetimes of the molecules in the ecited states are often measured by ...

    Text Solution

    |