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(a) In electrolysis of water, why is the...

(a) In electrolysis of water, why is the volume of gas collected over one electrode double that gas collected over the other electrode ?
(b) (i) What is observed whern a solution of potassium iodide is added to a solution of lead nitrate taken in a test tube ?
(ii) What type of reaction is this ?
(iii) Write a balanced chemical equation to represent the above reaction.

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