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The resistance of 1N solution of acetic ...

The resistance of `1N` solution of acetic acid is `250ohm`, when measured in a cell of cell constant `1.15 cm^(-1)`. The equivalent conductance `(` in `ohm^(-1) cm^(2)eq^(-1))` of `1N` acetic acid is

A

`4.6`

B

`9.2`

C

`18.4`

D

`0.023`

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The correct Answer is:
To find the equivalent conductance of a 1N solution of acetic acid, we can follow these steps: ### Step 1: Understand the relationship between resistance, cell constant, and conductance The conductance \( G \) of the solution can be calculated using the formula: \[ G = \frac{1}{R} \] where \( R \) is the resistance of the solution. ### Step 2: Calculate the conductance Given that the resistance \( R \) of the 1N acetic acid solution is \( 250 \, \Omega \): \[ G = \frac{1}{250 \, \Omega} = 0.004 \, \text{S} \, (\text{Siemens}) \] ### Step 3: Calculate the specific conductance \( K \) The specific conductance \( K \) can be calculated using the formula: \[ K = G \times \text{Cell Constant} \] Given that the cell constant is \( 1.15 \, \text{cm}^{-1} \): \[ K = 0.004 \, \text{S} \times 1.15 \, \text{cm}^{-1} = 0.0046 \, \text{S cm}^{-1} \] ### Step 4: Calculate the equivalent conductance \( \Lambda \) The equivalent conductance \( \Lambda \) is given by the formula: \[ \Lambda = \frac{K}{C} \] where \( C \) is the normality of the solution. For a 1N solution: \[ \Lambda = \frac{0.0046 \, \text{S cm}^{-1}}{1 \, \text{N}} = 0.0046 \, \text{S cm}^{-1} \] ### Step 5: Convert to appropriate units To express this in \( \text{ohm}^{-1} \text{cm}^2 \text{eq}^{-1} \): \[ \Lambda = 0.0046 \, \text{S cm}^{-1} \times 1000 \, \text{cm}^2/\text{eq} = 4.6 \, \text{ohm}^{-1} \text{cm}^2 \text{eq}^{-1} \] ### Final Answer The equivalent conductance of 1N acetic acid is: \[ \Lambda = 4.6 \, \text{ohm}^{-1} \text{cm}^2 \text{eq}^{-1} \]

To find the equivalent conductance of a 1N solution of acetic acid, we can follow these steps: ### Step 1: Understand the relationship between resistance, cell constant, and conductance The conductance \( G \) of the solution can be calculated using the formula: \[ G = \frac{1}{R} \] where \( R \) is the resistance of the solution. ...
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