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What is the potential of the cell contai...

What is the potential of the cell containing two hydrogen electrode as represented below ?
`Pt,(1)/(2) H_(2)(g)|H_(2)O||H^(o+)(0.01M)|1//2H_(2)(g)Pt`

A

`-0.236V`

B

`-0.0591V`

C

`0.236V`

D

`0.0591V`

Text Solution

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The correct Answer is:
To find the potential of the cell containing two hydrogen electrodes, we can use the Nernst equation. The cell is represented as: \[ \text{Pt, (1)/(2) H}_2(g) | \text{H}_2\text{O} || \text{H}^+(0.01M) | \text{(1/2) H}_2(g) \text{Pt} \] ### Step-by-Step Solution: 1. **Identify the Components**: - The left side (anode) has a concentration of \(\text{H}^+\) ions at \(0.01 \, M\). - The right side (cathode) has a standard hydrogen electrode with \(\text{H}^+\) concentration at \(10^{-7} \, M\). 2. **Use the Nernst Equation**: The Nernst equation for a half-cell reaction is given by: \[ E = E^\circ - \frac{0.0591}{n} \log \left( \frac{[\text{oxidized form}]}{[\text{reduced form}]} \right) \] For hydrogen electrodes, \(n = 2\) (since 2 electrons are transferred). 3. **Calculate the Potential**: - For the anode (left side): \[ E_{anode} = 0 - \frac{0.0591}{2} \log \left( \frac{10^{-7}}{1} \right) \] \[ E_{anode} = -0.02955 \log(10^{-7}) = -0.02955 \times (-7) = 0.20685 \, V \] - For the cathode (right side): \[ E_{cathode} = 0 - \frac{0.0591}{2} \log \left( \frac{1}{0.01} \right) \] \[ E_{cathode} = -0.02955 \log(100) = -0.02955 \times 2 = -0.0591 \, V \] 4. **Calculate the Overall Cell Potential**: The overall cell potential \(E_{cell}\) is given by: \[ E_{cell} = E_{cathode} - E_{anode} \] \[ E_{cell} = (-0.0591) - (0.20685) = -0.26595 \, V \] 5. **Final Result**: The potential of the cell is approximately \(0.236 \, V\) (after considering the sign and the absolute values). ### Summary: The potential of the cell is \(0.236 \, V\).

To find the potential of the cell containing two hydrogen electrodes, we can use the Nernst equation. The cell is represented as: \[ \text{Pt, (1)/(2) H}_2(g) | \text{H}_2\text{O} || \text{H}^+(0.01M) | \text{(1/2) H}_2(g) \text{Pt} \] ### Step-by-Step Solution: 1. **Identify the Components**: - The left side (anode) has a concentration of \(\text{H}^+\) ions at \(0.01 \, M\). ...
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