Home
Class 12
CHEMISTRY
E^(c-) for FeY^(c-)+e^(c-) rarr FeY^(2-)...


`E^(c-)` for `FeY^(c-)+e^(c-) rarr FeY^(2-)`

A

`0.13V`

B

`-0.636V`

C

`+0.636V`

D

`1.41V`

Text Solution

Verified by Experts

The correct Answer is:
a

For `underset((Fe^(+3)+e^(-) rarr Fe^(+2)))(FeY^(c-)+e^(-) rarr FeY^(2-)), ` the change is

`E^(c-)._(Fe^(+3),FeY^(c-)|Fe^(+2),FeY^(2-))`
`=E_(Fe^(+3)|Fe^(+2))^(c-)-(0.059)/(1)log.(K_(eq1))/(K_(eq2))`
`=0.77-(0.059)/(1)log.(1.3xx10^(25))/(2.1xx10^(14))=0.77-0.64=0.13V`.
Promotional Banner

Topper's Solved these Questions

  • ELECTROCHEMISTRY

    CENGAGE CHEMISTRY|Exercise Exerciseassertion -Reasoning|25 Videos
  • ELECTROCHEMISTRY

    CENGAGE CHEMISTRY|Exercise Exerciseinterger|8 Videos
  • ELECTROCHEMISTRY

    CENGAGE CHEMISTRY|Exercise Exercisemultiple Correct Ansers|53 Videos
  • D AND F BLOCK ELEMENTS

    CENGAGE CHEMISTRY|Exercise Archives Subjective|29 Videos
  • GENERAL PRINCIPLES AND PROCESS OF ISOLATION OF ELEMENTS

    CENGAGE CHEMISTRY|Exercise Archives (Subjective)|14 Videos

Similar Questions

Explore conceptually related problems

Given standard E^(c-): Fe^(3+)+3e^(-)rarrFe," "E^(c-)=-0.036 Fe^(2+)+2e^(-)rarr Fe," "E^(c-)=-0.440V The E^(c-) of Fe^(3+)+e^(-) rarr Fe^(2+) is

Redox reactions play a pivotal role in chemistry and biology. The values standard redox potential (E^(c-)) of two half cell reactions decided which way the reaction is expected to preceed. A simple example is a Daniell cell in which zinc goes into solution and copper sets deposited. Given below are a set of half cell reactions ( acidic medium ) along with their E^(c-)(V with respect to normal hydrogen electrode ) values. Using this data, obtain correct explanations for Question. I_(2)+2e^(-) rarr 2I^(c-)," "E^(c-)=0.54 Cl_(2)+2e^(-) rarr 2Cl^(c-), " "E^(c-)=1.36 Mn^(3+)+e^(-) rarr Mn^(2+), " "E^(c-)=1.50 Fe^(3+)+e^(-) rarr Fe^(2+)," "E^(c-)=0.77 O_(2)+4H^(o+)+4e^(-) rarr 2H_(2)O, " "E^(c-)=1.23 Sodium fusion extract obtained from aniline on treatment with iron (II) sulphate and H_(2)SO_(4) in the presence of air gives a Prussion blue precipitate. The blue colour is due to the formation of

Redox reactions play a pivotal role in chemistry and biology. The values standard redox potential (E^(c-)) of two half cell reactions decided which way the reaction is expected to preceed. A simple example is a Daniell cell in which zinc goes into solution and copper sets deposited. Given below are a set of half cell reactions ( acidic medium ) along with their E^(c-)(V with respect to normal hydrogen electrode ) values. Using this data, obtain correct explanations for Question. I_(2)+2e^(-) rarr 2I^(c-)," "E^(c-)=0.54 Cl_(2)+2e^(-) rarr 2Cl^(c-), " "E^(c-)=1.36 Mn^(3+)+e^(-) rarr Mn^(2+), " "E^(c-)=1.50 Fe^(3+)+e^(-) rarr Fe^(2+)," "E^(c-)=0.77 O_(2)+4H^(o+)+4e^(-) rarr 2H_(2)O, " "E^(c-)=1.23 While Fe^(3+) is stable, Mn^(3+) is not stable in acid solution because

Redox reactions play a pivotal role in chemistry and biology. The values standard redox potential (E^(c-)) of two half cell reactions decided which way the reaction is expected to preceed. A simple example is a Daniell cell in which zinc goes into solution and copper sets deposited. Given below are a set of half cell reactions ( acidic medium ) along with their E^(c-)(V with respect to normal hydrogen electrode ) values. Using this data, obtain correct explanations for Question. I_(2)+2e^(-) rarr 2I^(c-)," "E^(c-)=0.54 Cl_(2)+2e^(-) rarr 2Cl^(c-), " "E^(c-)=1.36 Mn^(3+)+e^(-) rarr Mn^(2+), " "E^(c-)=1.50 Fe^(3+)+e^(-) rarr Fe^(2+)," "E^(c-)=0.77 O_(2)+4H^(o+)+4e^(-) rarr 2H_(2)O, " "E^(c-)=1.23 Among the following, identify the correct statement.

For the reaction : A+2B^(3+) rarr 2B^(2+)+A^(2+) E^(c-) of the given redox reaction is : A^(2+)+2e^(-) rarr A E^(c-)=Xv B^(3+)+e^(-) rarr B^(2+) E^(c-)=yV

Half cell reactions for some electrodes are given below I. A + e^(-) rarr A^(-) , E^(@) = 0.96V II. B^(-) + e^(-) rarr B^(2-) , E^(@) = -0.12V III. C^(+) + e^(-) rarr C, E^(@) =+0.18V IV. D^(2+) + 2e^(-) rarr D, E^(@) = -1.12V Largest potential will be generated in which cell?

E^(c-) of some elements are given as : {:(I_(2)+2e^(-)rarr 2I^(c-),,,,E^(c-)=0.54V),(MnO_(4)^(c-)+8H^(o+)+5e^(-)rarr Mn^(2+)+4H_(2)O,,,,E^(c-)=1.52V),(Fe^(3+)+e^(-)rarr Fe^(2+),,,,E^(c-)=0.77V),(Sn^(4+)+2e^(-)rarr Sn^(2+),,,,E^(c-)=0.1V):} a. Select the stronges reductant and weakes oxidant among these elements. b. Select the weakest reductant and strongest oxidant among these elements.

Given electrode potentials asre Fe^(3+)+e^(-) rarr Fe^(2+)," "E^(c-)=0.771V I_(2)+2e^(-) rarr 2I^(c-)," "E^(c-)=0.536V E^(c-)._(cell) for the cell reaction, Fe^(3+)+2I^(c-) rarr Fe^(2+)+I_(2) is

Given that I_(2)+2e^(-) rarr 2I^(c-)," "E^(c-)=0.54V Br_(2)+2e^(-) rarr 2Br^(-)," "E^(c-)=1.69V Predict which of the following is true.

Given : Fe^(2+)(aq)+2e^(-) rarr Fe(s), " "E^(c-)=-0.44V Al^(3)+3e^(-) rarr Al(s)," "E^(c-)=-1.66V Br^(2+)+2e^(-)rarr 2Br^(c-)(aq)" "E^(c-)=-1.08V The decreasing order of reducing power is ……………………………….. .

CENGAGE CHEMISTRY-ELECTROCHEMISTRY-Exercises Ingle Correct
  1. The electricity conductivity of a solution serves as a means of determ...

    Text Solution

    |

  2. A constant current was passed through a solution of AuCl(4)^(c-) ion b...

    Text Solution

    |

  3. E^(c-) for FeY^(c-)+e^(c-) rarr FeY^(2-)

    Text Solution

    |

  4. Calculate E^(c-) for the reactions : ZnY^(2-)hArrZn(s)+Y^(4-) where...

    Text Solution

    |

  5. The solubility product of Pb(3)(AsO(4))(2) is 4.1xx10^(-36). E^(c-) fo...

    Text Solution

    |

  6. A cell is to be constructed to show a redox change : Cr+2Cr^(3+)hArr...

    Text Solution

    |

  7. E^(c-) for Cr^(3+)+3e^(-) rarr Cr and Cr^(3+)+e^(-) rarr Cr^(2+) are -...

    Text Solution

    |

  8. The efficiency of a fuel cell si 80% and the standard heat of reaction...

    Text Solution

    |

  9. The E(cell) for a given cell is 1.2346 and 1.2340V at 300K and 310K, ...

    Text Solution

    |

  10. A curent of 3A was passed for 1 hour through an electrolyte solution o...

    Text Solution

    |

  11. The E^(c-) for Cu^(2+)//Cu^(o+),Cu^(o+)//Cu,Cu^(2+)//Cu, are 0.15V,0.5...

    Text Solution

    |

  12. Total charge required to convert three moles of Mn(2)O(4) to MnO(4)^(c...

    Text Solution

    |

  13. A current of 965A is passed for 1 s through 1L solution of 0.02N NiSO(...

    Text Solution

    |

  14. For the given cell Pt(D(2)|D^(o+))||H^(o+)|Pt(H(2)), if E^(c-).(D(2)|D...

    Text Solution

    |

  15. What is E^(c).(red) for the reaction: Cu^(2+)+2e^(-) rarr Cu in the ha...

    Text Solution

    |

  16. The combustion of butane in O(2) at 1 bar and 298K shows a decrease in...

    Text Solution

    |

  17. A half cell reaction Ag(2)S(s)+2e^(-) rarr 3Ag(s)+S^(2-) is carried ou...

    Text Solution

    |

  18. Which one is wrong if electrolysis of CH(3)COONa(aq) is made using Pt ...

    Text Solution

    |

  19. The calomel and quinhydrone electrodes are reversible with respect to ...

    Text Solution

    |

  20. The EMF of Ni-Cad battery is dependent of :

    Text Solution

    |