Home
Class 12
CHEMISTRY
The E^(c-) for Cu^(2+)//Cu^(o+),Cu^(o+)/...

The `E^(c-)` for `Cu^(2+)//Cu^(o+),Cu^(o+)//Cu,Cu^(2+)//Cu,` are `0.15V,0.50V` and `0.325V`, respectively. The redox cell showing redox reaction `2Cu^(o+) rarr Cu^(2+)+Cu` is made. `E^(c-)` of this cell reaction and `DeltaG^(c-)` may be

A

`E^(c-)=0.175V or E^(c-)=0.350V`

B

`n=1 or 2`

C

`Delta G^(c-)=-33.775k J`

D

All of these

Text Solution

Verified by Experts

The correct Answer is:
d

`2Cu^(o+) rarr Cu^(2+)+Cu,`
Cell `I:Cu^(o+) rarr Cu^(2+)+e)`
`Cu^(o+)+e rarr Cu `
`ulbar(2Cu^(o+) rarr Cu^(2+)+Cu)`
`E^(c-)=-0.15+0.50`
`=+0.35V`
`n=1`
Cell `II:Cu rarr Cu^(2+)+2e`
`2Cu^(o+)+2e rarr2Cu`
`ulbar (2Cu^(o+) rarr Cu^(2+)+Cu)`
`E^(c-)=-0.325+0.50`
`=+0.175V`
`n=2`
Promotional Banner

Topper's Solved these Questions

  • ELECTROCHEMISTRY

    CENGAGE CHEMISTRY|Exercise Exerciseassertion -Reasoning|25 Videos
  • ELECTROCHEMISTRY

    CENGAGE CHEMISTRY|Exercise Exerciseinterger|8 Videos
  • ELECTROCHEMISTRY

    CENGAGE CHEMISTRY|Exercise Exercisemultiple Correct Ansers|53 Videos
  • D AND F BLOCK ELEMENTS

    CENGAGE CHEMISTRY|Exercise Archives Subjective|29 Videos
  • GENERAL PRINCIPLES AND PROCESS OF ISOLATION OF ELEMENTS

    CENGAGE CHEMISTRY|Exercise Archives (Subjective)|14 Videos

Similar Questions

Explore conceptually related problems

The E^(o) for half cells Fe//Fe^(2+) and Cu//Cu^(2+) are –0.44 V and +0.32 V respectively. Then which of these is true?

The standard reduction potentials for Cu^(2+)//Cu and Cu^(2+)//Cu^(+) are 0.337 V and 0.153 V respectively. The standard electrode potenials of Cu^(+)//Cu half cell is :

The standard reduction potential of Cu^(2+)//Cu and Cu^(2+)//Cu^(+) are 0.339 V and 0.153 V respectively. The standard electrode potential of Cu^(+)//Cu half cell is :

The standard reduction potentials of Cu^(2+)//Cu and Cu^(2+)//Cu^(+) are 0.337 V and 0.153V respectively. The standard electrode potential of Cu^(+)//Cu half-cell is

The standard reduction potentials of Cu^(2+)|Cu and Cu^(2+)|Cu^(o+) are 0.337V and 0.153V , respectively. The standard electrode potential fo Cu^(o+)|Cu half cell is

The electrode potentials for Cu^(2+)+e^(-)toCu^(+) and Cu^(+)e^(-)toCu_(s) are +0.15 V and +0.50V respectively the value of E_((Cu^(2+))/(Cu))^(@) will be?

CENGAGE CHEMISTRY-ELECTROCHEMISTRY-Exercises Ingle Correct
  1. The E(cell) for a given cell is 1.2346 and 1.2340V at 300K and 310K, ...

    Text Solution

    |

  2. A curent of 3A was passed for 1 hour through an electrolyte solution o...

    Text Solution

    |

  3. The E^(c-) for Cu^(2+)//Cu^(o+),Cu^(o+)//Cu,Cu^(2+)//Cu, are 0.15V,0.5...

    Text Solution

    |

  4. Total charge required to convert three moles of Mn(2)O(4) to MnO(4)^(c...

    Text Solution

    |

  5. A current of 965A is passed for 1 s through 1L solution of 0.02N NiSO(...

    Text Solution

    |

  6. For the given cell Pt(D(2)|D^(o+))||H^(o+)|Pt(H(2)), if E^(c-).(D(2)|D...

    Text Solution

    |

  7. What is E^(c).(red) for the reaction: Cu^(2+)+2e^(-) rarr Cu in the ha...

    Text Solution

    |

  8. The combustion of butane in O(2) at 1 bar and 298K shows a decrease in...

    Text Solution

    |

  9. A half cell reaction Ag(2)S(s)+2e^(-) rarr 3Ag(s)+S^(2-) is carried ou...

    Text Solution

    |

  10. Which one is wrong if electrolysis of CH(3)COONa(aq) is made using Pt ...

    Text Solution

    |

  11. The calomel and quinhydrone electrodes are reversible with respect to ...

    Text Solution

    |

  12. The EMF of Ni-Cad battery is dependent of :

    Text Solution

    |

  13. The electrode with reaction :Cr(2)O(7)^(2-)(aq)+14H^(o+)(aq)+6e^(-) ra...

    Text Solution

    |

  14. For a given reaction :M^((x+n))+n e^(-)rarr M^(c+),E^(c-).(red) is kn...

    Text Solution

    |

  15. Select the wrong statement.

    Text Solution

    |

  16. Select the correct statement.

    Text Solution

    |

  17. From the following information, calculate the solubility product of A...

    Text Solution

    |

  18. The strongest oxidizing agent among the following is

    Text Solution

    |

  19. The weakest oxidizing agent among the following is

    Text Solution

    |

  20. Suppose that gold is being plated onto another metal in a electrolytic...

    Text Solution

    |