Home
Class 12
CHEMISTRY
The electrode with reaction :Cr(2)O(7)^(...

The electrode with reaction `:Cr_(2)O_(7)^(2-)(aq)+14H^(o+)(aq)+6e^(-) rarr 2Cr^(3+)(aq)+7H_(2)O` can be represented as

A

`Pt|H^(o+)(aq),Cr_(2)O_(7)^(2-)(aq)`

B

`Pt|H^(o+)(aq),Cr_(2)O_(7)^(2-)(aq),Cr^(3+)(aq)`

C

`Pt_(H2)|H^(o+)(aq),Cr_(2)O_(7)^(2-)`

D

`Pt_(H2)|H^(o+)(aq),Cr_(2)O_(7)^(2-)(aq),Cr^(3+)(aq)`

Text Solution

Verified by Experts

The correct Answer is:
d

`Cr_(2)O_(7)^(2-)` reduces to `2Cr^(3+)`, so much be represented at cathode. `H_(2)` is oxidized to `2H^(o+)`, so must be representedd at anode. So the cell representation is as shown in `(d)`.
Promotional Banner

Topper's Solved these Questions

  • ELECTROCHEMISTRY

    CENGAGE CHEMISTRY|Exercise Exerciseassertion -Reasoning|25 Videos
  • ELECTROCHEMISTRY

    CENGAGE CHEMISTRY|Exercise Exerciseinterger|8 Videos
  • ELECTROCHEMISTRY

    CENGAGE CHEMISTRY|Exercise Exercisemultiple Correct Ansers|53 Videos
  • D AND F BLOCK ELEMENTS

    CENGAGE CHEMISTRY|Exercise Archives Subjective|29 Videos
  • GENERAL PRINCIPLES AND PROCESS OF ISOLATION OF ELEMENTS

    CENGAGE CHEMISTRY|Exercise Archives (Subjective)|14 Videos

Similar Questions

Explore conceptually related problems

What type of a battery is lead storage battery? Write the anode and cathode reactions and the overall cell reaction occurring in the operation of a lead storage battery. (b) Calucluate the potential for half-cell containing. 0.10 M K_(2)Cr_(2)O_(7)(aq), 0.20 M Cr^(3+) (aq) and 1.0 xx 10^(-4) M H^(+) (aq) The half -cell reaction is Cr_(2)O_(7)^(2-) (aq) + 4H^(+) (aq) + 6 e^(-) to 2 Cr^(3+) (aq) + 7H_(2)O(l) and the standard electron potential is given as E^(o) = 1.33V .

The cell reaction Cr_2O_7^(2-)(aq)+14H^+(aq)+6Fe^(2+)(aq)to6Fe^(3+)(aq)+2Cr^(3+)(aq)+7H_2O(l) is best represented by:

Calculate the potential for a half cell reaction containing 0.1 M K_(2)Cr_(2)O_(7), 0.20 M Cr^(3+)(aq) and 1.0xx10^(-4) M H^(+)(aq) . The half cell reaction is : Cr_(2)O_(7)^(2-)(aq)+14 H^(+)(aq)+6e^(-)to2 Cr^(3+)(aq)+7H_(2)O (l) The standard electrode potential (E^(@))=1.33 V .

In the reaction: Cr_(2)O_(7)^(2-) + 14H^(o+) + 6I^(Ө) rarr2Cr^(3+) + 3H_(2)O + 3I_(2) Which element is reduced?

For reaction : Cr_(2)O_(7)^(-2)+14H^(+)rarr2Cr^(+3)+7H_(2)O , How many e^(-)s are required

The standard electrode potential for the following reaction is +1.33V . What is the potential at pH =2.0 ? Cr_(2)O_(7)^(2-)(aq,1M)+14H^(+)(aq)+6e^(-) rarr 2Cr^(3+)(aq. 1M)+7H_(2)O(l)

CENGAGE CHEMISTRY-ELECTROCHEMISTRY-Exercises Ingle Correct
  1. The calomel and quinhydrone electrodes are reversible with respect to ...

    Text Solution

    |

  2. The EMF of Ni-Cad battery is dependent of :

    Text Solution

    |

  3. The electrode with reaction :Cr(2)O(7)^(2-)(aq)+14H^(o+)(aq)+6e^(-) ra...

    Text Solution

    |

  4. For a given reaction :M^((x+n))+n e^(-)rarr M^(c+),E^(c-).(red) is kn...

    Text Solution

    |

  5. Select the wrong statement.

    Text Solution

    |

  6. Select the correct statement.

    Text Solution

    |

  7. From the following information, calculate the solubility product of A...

    Text Solution

    |

  8. The strongest oxidizing agent among the following is

    Text Solution

    |

  9. The weakest oxidizing agent among the following is

    Text Solution

    |

  10. Suppose that gold is being plated onto another metal in a electrolytic...

    Text Solution

    |

  11. Chromium plating is applied by electrolysis to objects suspended in a ...

    Text Solution

    |

  12. 20 Ml of KOH solution was titrated with 0.20 M H(2)SO(4) solution in a...

    Text Solution

    |

  13. What is the cell entropy change ( in J K ^(-1)) of the following cell...

    Text Solution

    |

  14. k=4.95xx10^(-5) S cm^(-1) for a 0.001 M solution. The reciprocal of th...

    Text Solution

    |

  15. What is the value of pK(b)(CH(3)COO^(c-)) if wedge^(@).(m)=390 S cm^(-...

    Text Solution

    |

  16. In Hall's process , in the production of Al, carbon is used as the ano...

    Text Solution

    |

  17. DeltaG^(c-) or the reaction is , 4Al+3O(2)+6H(2)O+4overset(c-)(O)H r...

    Text Solution

    |

  18. Cu^(2+)+2e^(-) rarr Cu. For this, graph between E(red) versus ln[Cu^(2...

    Text Solution

    |

  19. A cell Cu|Cu^(2+)||Ag^(o+)|Ag inintially contains 2 M Ag^(o+) and 2 M ...

    Text Solution

    |

  20. The value of reaction quotient Q for the cell Zn(s)|Zn^(2+)(0.01M)||...

    Text Solution

    |