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The rate of reaction is expressed as : ...

The rate of reaction is expressed as :
`(1)/(2)(+d)/(d t)[C] = (1)/(3)(-d)/(d t)[D] = (1)/(4)(+d)/(d t)[A] = -(d)/(d t)[B]`
The reaction is:

A

`(1)/(4)A + (1)/(2)(C ) rarr B+(1)/(3)D`

B

`4A + 2C rarr B + 3D`

C

`B + 3D rarr 4A + 2C`

D

(d) `B + (1)/(3)D rarr (1)/(4)A + (1)/(2)C`

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The correct Answer is:
To determine the reaction based on the given rate expression, we can follow these steps: ### Step 1: Analyze the Rate Expression The rate of reaction is given as: \[ \frac{1}{2} \left( \frac{d[C]}{dt} \right) = \frac{1}{3} \left( -\frac{d[D]}{dt} \right) = \frac{1}{4} \left( \frac{d[A]}{dt} \right) = -\left( \frac{d[B]}{dt} \right) \] ### Step 2: Identify the Stoichiometric Coefficients From the rate expression, we can identify the stoichiometric coefficients for each species involved in the reaction: - For \([C]\), the coefficient is \(2\) (since it is in the denominator). - For \([D]\), the coefficient is \(3\) (since it is in the denominator). - For \([A]\), the coefficient is \(4\) (since it is in the denominator). - For \([B]\), the coefficient is \(1\) (since it is in the denominator). ### Step 3: Write the Balanced Chemical Equation Based on the stoichiometric coefficients, we can write the balanced chemical equation: \[ 3D + 4A \rightarrow 2C + B \] ### Step 4: Confirm the Reaction We can confirm that the rates of disappearance of reactants and formation of products are consistent with the coefficients: - The rate of disappearance of \(D\) is \(-\frac{d[D]}{dt}\) and has a coefficient of \(3\). - The rate of disappearance of \(A\) is \(-\frac{d[A]}{dt}\) and has a coefficient of \(4\). - The rate of formation of \(C\) is \(\frac{d[C]}{dt}\) and has a coefficient of \(2\). - The rate of formation of \(B\) is \(\frac{d[B]}{dt}\) and has a coefficient of \(1\). ### Final Reaction Thus, the final balanced reaction can be expressed as: \[ 3D + 4A \rightarrow 2C + B \]

To determine the reaction based on the given rate expression, we can follow these steps: ### Step 1: Analyze the Rate Expression The rate of reaction is given as: \[ \frac{1}{2} \left( \frac{d[C]}{dt} \right) = \frac{1}{3} \left( -\frac{d[D]}{dt} \right) = \frac{1}{4} \left( \frac{d[A]}{dt} \right) = -\left( \frac{d[B]}{dt} \right) \] ...
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