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For a chemical reaction A rarr B, the ra...

For a chemical reaction `A rarr B`, the rate of reaction increases by a factor of `1.837` when the concentration of `A` is increased by `1.5` time. The order of reaction with respect to `A` is:

A

`1`

B

`1.5`

C

`2`

D

`-1`

Text Solution

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The correct Answer is:
To determine the order of the reaction with respect to A for the reaction \( A \rightarrow B \), we can follow these steps: ### Step 1: Write the rate law expression The rate of the reaction can be expressed as: \[ R = k[A]^x \] where \( R \) is the rate of reaction, \( k \) is the rate constant, \( [A] \) is the concentration of reactant A, and \( x \) is the order of the reaction with respect to A. ### Step 2: Set up the initial and new rates Let the initial concentration of A be \( [A] \). The initial rate of reaction \( R_1 \) can be expressed as: \[ R_1 = k[A]^x \] When the concentration of A is increased by 1.5 times, the new concentration becomes \( 1.5[A] \). The new rate of reaction \( R_2 \) is: \[ R_2 = k(1.5[A])^x = k \cdot 1.5^x \cdot [A]^x \] ### Step 3: Relate the rates According to the problem, the new rate \( R_2 \) is 1.837 times the initial rate \( R_1 \): \[ R_2 = 1.837 R_1 \] Substituting the expressions for \( R_1 \) and \( R_2 \): \[ k \cdot 1.5^x \cdot [A]^x = 1.837 \cdot k[A]^x \] ### Step 4: Simplify the equation Since \( k[A]^x \) appears on both sides, we can cancel it out (assuming \( [A] \neq 0 \)): \[ 1.5^x = 1.837 \] ### Step 5: Solve for \( x \) To find \( x \), we take logarithms or recognize that \( 1.5^x = 1.837 \). We can express this as: \[ x = \log_{1.5}(1.837) \] Using the change of base formula: \[ x = \frac{\log(1.837)}{\log(1.5)} \] Calculating this gives: \[ x \approx 1.5 \] ### Conclusion Thus, the order of the reaction with respect to A is: \[ \text{Order} = 1.5 \]

To determine the order of the reaction with respect to A for the reaction \( A \rightarrow B \), we can follow these steps: ### Step 1: Write the rate law expression The rate of the reaction can be expressed as: \[ R = k[A]^x \] where \( R \) is the rate of reaction, \( k \) is the rate constant, \( [A] \) is the concentration of reactant A, and \( x \) is the order of the reaction with respect to A. ...
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