Home
Class 12
CHEMISTRY
Given that the temperature coefficient f...

Given that the temperature coefficient for the saponification of ethylacetate by `NaOH` is `1.75`. Calculate the activation energy.

Text Solution

Verified by Experts

`(k_(2))/(k_(1))= 1.75`, `T_(1)= 298 k, T_(2)= 308K`
(Since temperature coefficient is the ratio of rate cosntants at `35^(@)C and 25^(@)C)`
`2.303 log.(k_(2))/(k_(1))=(E_(a))/(R )[(T_(2)-T_(1))/(T_(1)T_(2))]`
`2.303 log 1.75=(E_(a))/(1.987)xx(308-298)/(308xx298)`
`E_(a)=(2.303xx308xx298xx1.987)/(10) log 1.75 cal mol^(-1)`
`= 10.207 kcal mol^(-1)`
`10.207 kcal mol^(-1)`
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL KINETICS

    CENGAGE CHEMISTRY|Exercise Solved Example|52 Videos
  • CHEMICAL KINETICS

    CENGAGE CHEMISTRY|Exercise Ex 4.1 (Objective)|9 Videos
  • CARBOXYLIC ACIDS AND THEIR DERIVATIVES

    CENGAGE CHEMISTRY|Exercise Exercises Archives (Analytical And Descriptive)|34 Videos
  • COORDINATION COMPOUNDS

    CENGAGE CHEMISTRY|Exercise Archives Subjective|18 Videos

Similar Questions

Explore conceptually related problems

The rates of most reaction double when their temperature is raised from 298K to 308K . Calculate their activation energy.

Given the following data, calculate coefficient of variation:

The rates of most reactions double when their temperature is raised from 298 K to 308 K. Calculate their activation energy.

The temperature coefficient of a reaction is 2 and the rate of reaction at 25° C is 3mol L^(-1) min^(-1) . Calculate the rate at 75^(@) C

CENGAGE CHEMISTRY-CHEMICAL KINETICS-Archives Subjective
  1. Given that the temperature coefficient for the saponification of ethyl...

    Text Solution

    |

  2. Rate of a reaction A + B rarr Product, is given as a function of diffe...

    Text Solution

    |

  3. A first order reaction is 20% complete in 10 min. Calculate (a) the sp...

    Text Solution

    |

  4. While studying the decompoistion of gaseous N(2)O(5), it is observed t...

    Text Solution

    |

  5. A first order gas reaction has k = 1.5 xx 10^(-6) s^(-1) at 200^(@)C. ...

    Text Solution

    |

  6. A first order reaction is 50% completed in 30 min at 27^(@)C and in 10...

    Text Solution

    |

  7. In a Arrhenius equation for a certain reaction, the values of A and E(...

    Text Solution

    |

  8. The decomposition of N(2)O(5) according to the equation: 2N(2)O(5)(g) ...

    Text Solution

    |

  9. Two reaction, (I)A rarr Products and (II) B rarr Products, follow firs...

    Text Solution

    |

  10. The gas phase decomposition of dimethyl ether follows first order kine...

    Text Solution

    |

  11. A first order reaction A rarr B requires activation energy of 70 kJ mo...

    Text Solution

    |

  12. form the following data for the reaction between A and B, (a) Cal...

    Text Solution

    |

  13. At 380^(@)C , the half-life periof for the first order decompoistion o...

    Text Solution

    |

  14. The ionization constant of overset(o+)(NH(4)) ion in water is 5.6 xx 1...

    Text Solution

    |

  15. The time required for 10% completion of a first order reaction at 298 ...

    Text Solution

    |

  16. The rate constant for the first order decompoistion of a certain react...

    Text Solution

    |

  17. For the equation N(2)O(5)(g)=2NO(2)(g)+(1//2)O(2)(g), calculate the ...

    Text Solution

    |

  18. The rate constant of a reaction is 1.5 xx 10^(7)s^(-1) at 50^(@)C and ...

    Text Solution

    |

  19. The rate constant for an isomerization reaction, A rarr B is 4.5 xx 10...

    Text Solution

    |

  20. A hydrogenation reaction is carried out at 500 K. If the same reaction...

    Text Solution

    |

  21. The vapour pressure of two miscible liquids (A) and (B) are 300 and 50...

    Text Solution

    |