Home
Class 12
CHEMISTRY
In a Arrhenius equation for a certain re...

In a Arrhenius equation for a certain reaction, the values of `A and E_(a)` ( energy of activation)are `4xx10^(13)s^(-1)` and `98.6KJ mol^(-1)`, respectively. If the reaction of first order at, what temperature will its life periof be `10 min`.

Text Solution

Verified by Experts

`k=Ae^(-E_(a)//RT)`
`= 4xx10^(13)e^(-(98.6xx10^(3))//8.344xxT)`
For first orser, `k=(0.693)/(600)s^(-1)`
`(0.963)/(600)= 1og^(4)xx10^(13) -(98.6xx10^(3))/(8.314xx2.303xxT)`
`T= 311.35K`
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL KINETICS

    CENGAGE CHEMISTRY|Exercise Solved Example|52 Videos
  • CHEMICAL KINETICS

    CENGAGE CHEMISTRY|Exercise Ex 4.1 (Objective)|9 Videos
  • CARBOXYLIC ACIDS AND THEIR DERIVATIVES

    CENGAGE CHEMISTRY|Exercise Exercises Archives (Analytical And Descriptive)|34 Videos
  • COORDINATION COMPOUNDS

    CENGAGE CHEMISTRY|Exercise Archives Subjective|18 Videos

Similar Questions

Explore conceptually related problems

In the Arrhenius equation for a centrain, the value of A and E_a (activation energy ) are 4 xx 10^(13)s^(-1) and 98.6 kJ mol^(51) respectively. If the reaction is of first order, at what termperature will its half-life preriod be 10 min ?

In Arrhenius equation for a certain reaction , the values of A and E_(a) (activation energy are 4xx10^(13) "sec"^(-1) and 98.6 kJ "mol"^(-1) respectively. At what temeperatue, the reaction will have specific constant 1.1xx10^(-3) "sec"^(-1) ?

CENGAGE CHEMISTRY-CHEMICAL KINETICS-Archives Subjective
  1. In a Arrhenius equation for a certain reaction, the values of A and E(...

    Text Solution

    |

  2. Rate of a reaction A + B rarr Product, is given as a function of diffe...

    Text Solution

    |

  3. A first order reaction is 20% complete in 10 min. Calculate (a) the sp...

    Text Solution

    |

  4. While studying the decompoistion of gaseous N(2)O(5), it is observed t...

    Text Solution

    |

  5. A first order gas reaction has k = 1.5 xx 10^(-6) s^(-1) at 200^(@)C. ...

    Text Solution

    |

  6. A first order reaction is 50% completed in 30 min at 27^(@)C and in 10...

    Text Solution

    |

  7. In a Arrhenius equation for a certain reaction, the values of A and E(...

    Text Solution

    |

  8. The decomposition of N(2)O(5) according to the equation: 2N(2)O(5)(g) ...

    Text Solution

    |

  9. Two reaction, (I)A rarr Products and (II) B rarr Products, follow firs...

    Text Solution

    |

  10. The gas phase decomposition of dimethyl ether follows first order kine...

    Text Solution

    |

  11. A first order reaction A rarr B requires activation energy of 70 kJ mo...

    Text Solution

    |

  12. form the following data for the reaction between A and B, (a) Cal...

    Text Solution

    |

  13. At 380^(@)C , the half-life periof for the first order decompoistion o...

    Text Solution

    |

  14. The ionization constant of overset(o+)(NH(4)) ion in water is 5.6 xx 1...

    Text Solution

    |

  15. The time required for 10% completion of a first order reaction at 298 ...

    Text Solution

    |

  16. The rate constant for the first order decompoistion of a certain react...

    Text Solution

    |

  17. For the equation N(2)O(5)(g)=2NO(2)(g)+(1//2)O(2)(g), calculate the ...

    Text Solution

    |

  18. The rate constant of a reaction is 1.5 xx 10^(7)s^(-1) at 50^(@)C and ...

    Text Solution

    |

  19. The rate constant for an isomerization reaction, A rarr B is 4.5 xx 10...

    Text Solution

    |

  20. A hydrogenation reaction is carried out at 500 K. If the same reaction...

    Text Solution

    |

  21. The vapour pressure of two miscible liquids (A) and (B) are 300 and 50...

    Text Solution

    |