Home
Class 12
CHEMISTRY
Conisder a mechanism in which a single r...

Conisder a mechanism in which a single reactant profuces several Products by the following parallel first order reactions :
`A overset(k_(1))rarrB, A overset(k_(2))rarrC A overset(k_(3))rarrD`
Write the rate expresison for `[A]`.

Text Solution

Verified by Experts

`(-d[A])/(dt)=k_(1)[A]+k_(2)[A]+k_(3)[A]`
`=(k_(1)+k_(2)+k_(3))[A]`
`=k[A]`
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL KINETICS

    CENGAGE CHEMISTRY|Exercise Ex 4.1 (Objective)|9 Videos
  • CHEMICAL KINETICS

    CENGAGE CHEMISTRY|Exercise Ex 4.2 (Objective)|10 Videos
  • CHEMICAL KINETICS

    CENGAGE CHEMISTRY|Exercise Archives Subjective|23 Videos
  • CARBOXYLIC ACIDS AND THEIR DERIVATIVES

    CENGAGE CHEMISTRY|Exercise Exercises Archives (Analytical And Descriptive)|34 Videos
  • COORDINATION COMPOUNDS

    CENGAGE CHEMISTRY|Exercise Archives Subjective|18 Videos

Similar Questions

Explore conceptually related problems

Conisder parallel reaction: Aoverset(k_(1))rarrB, 2Aoverset(k_(2))rarrC+D What would be the rate expresison for [A] ?

Mechanism of the reaction is: A overset(k_(1))rarrB, 2Aoverset(k_(2))rarr C + D What is (-d[A])/(dt) ?

A consecutive reaction, A overset(K_(1))(rarr)B overset(K_(2))(rarr)C is characterised by:

In the sequence of reaction, L overset(k_(1))rarr M overset(k_(2))rarr N overset(k_(3))rarrO k_(3) gt k_(2) gt k_(1) The rate determining step of the reaction is :

For the consecutive unimolecular first order reaction A overset(k_(1))rarr R overset(k_(2))rarr S , the concentration of component A , C_(A) at any time t is given by

Predict the product C in the following series of reactions , CH_3-COOH overset(PCl_5)rarrAunderset("Anhyd . AlCl_3)overset(C_6H_6)rarrB overset(CH_3MgBr)rarrC

For the reaction, H_(2)+I_(2)overset(k_(1))underset(k_(2))hArr2HI . The rate law expression is :

CENGAGE CHEMISTRY-CHEMICAL KINETICS-Solved Example
  1. H(2)(g) + Ar(g) underset(k(r ))overset(k(f))hArr 2H(g)+Ar(g) k(f)= 2...

    Text Solution

    |

  2. Conisder parallel reaction: Aoverset(k(1))rarrB, 2Aoverset(k(2))rarr...

    Text Solution

    |

  3. Conisder a mechanism in which a single reactant profuces several Produ...

    Text Solution

    |

  4. A proposed mechanism for a reaction ArarrB is A underset(k(2))overse...

    Text Solution

    |

  5. Bicyclohexane was found to undergo two parallel first order rearrangem...

    Text Solution

    |

  6. Trans 1,2-dideuterocyclopropane (A) undergoes a first order decompoist...

    Text Solution

    |

  7. The decompoistion of Cl(2)O(7) at 400 K in gas phase to Cl(2) and O(2)...

    Text Solution

    |

  8. Ethylene is profuced by C(4)H(8)("cyclobutane")overset(Delta)rarr2C(...

    Text Solution

    |

  9. form the following data for the decompoistion of N(2)O(5) in carbon te...

    Text Solution

    |

  10. 1.0 mL of ethyl acetate was added to 25 mL of N//2 HCl, 2 mL of the mi...

    Text Solution

    |

  11. The inverison of cane sugar was studied is HCl at 298 K. The following...

    Text Solution

    |

  12. An exothermic reaction XrarrY has an activation energy of 90kJ mol^(-1...

    Text Solution

    |

  13. Refer picture given below. (a) Calculate DeltaH for the reaction and...

    Text Solution

    |

  14. Calculate the activation energy of a reaction whose reaction rate at 3...

    Text Solution

    |

  15. The activation energy of a reaction is 94.14 kJ mol^(-1) and the value...

    Text Solution

    |

  16. The rate constant of a reaction is 1.5 xx 10^(7)s^(-1) at 50^(@)C and ...

    Text Solution

    |

  17. For two reactions (i) P rarr Product and (ii) Q rarr Product, the orde...

    Text Solution

    |

  18. For two firstorder reactions having same concentration of A and B at t...

    Text Solution

    |

  19. The Arrehenius equation for the rate constant of decompoistion of meth...

    Text Solution

    |

  20. The activation energy of the reaction: A + B rarr Products is 105.73 k...

    Text Solution

    |