Home
Class 12
CHEMISTRY
Half life id independent of the concentr...


Half life id independent of the concentration of `A`. After `10 mi n` volume of `N_(2)` gas is `10 L` and after complete reaction is `50 L`. Hence, the rate constant is

A

`(2.303)/(10) log 5 mi n^(-1)`

B

`(2.303)/(10) log 1.25 mi n^(-1)`

C

`(2.303)/(10) log 2 mi n^(-1)`

D

`(2.303)/(10) log 4 mi n^(-1)`

Text Solution

Verified by Experts

The correct Answer is:
B

It follows first order kinetics Since `T_(50)` is independent of concentration.

Hence, `x=10L, a= 50L`
`:. k=(2.303)/(10) log.(50)/(40)=(2.303)/(10)log 1.25 min^(-1)`
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL KINETICS

    CENGAGE CHEMISTRY|Exercise Exercises Assertion-Reasoning|22 Videos
  • CHEMICAL KINETICS

    CENGAGE CHEMISTRY|Exercise Exercises Integer|15 Videos
  • CHEMICAL KINETICS

    CENGAGE CHEMISTRY|Exercise Exercises Multiple Correct|34 Videos
  • CARBOXYLIC ACIDS AND THEIR DERIVATIVES

    CENGAGE CHEMISTRY|Exercise Exercises Archives (Analytical And Descriptive)|34 Videos
  • COORDINATION COMPOUNDS

    CENGAGE CHEMISTRY|Exercise Archives Subjective|18 Videos

Similar Questions

Explore conceptually related problems

Half- life is independent of conc. of A. After 10 minutes volume N_(2) gas is 10 L and after complete reaction 50 L. Hence rate constant in "min"^(–1) :

For reaction \(X \rightarrow Y+Z\) half life is independent of the concentration of X. After "20" minutes volume of gas "Z" is "10mL and after very long time it is "50mL" ,the rate constant is

For reaction X rarr Y+Z half life is independent of the concentration of X .After 20 minutes volume of gas Z is 10mL and after very long time it is 50mL ,the rate constant is : 1) (2.303)/(20)log5 2) (2.303)/(20)log1.25 3) (2.303)/(10)log2 4) (2.303)/(20)log4

Half life of reaction : H_(2)O_(2)(aq) rarr H_(2)O(l)+(1)/(2)O_(2)(g) is independent of initial concentration of H_(2)O_(2) volume of O_(2) gas after 20 minute is 5L at 1 atm and 27^(@)C and after completion of reaction is 50L . The rate constant is :

The compoistion of N_(2)O_(5) is a first order reaction represented by: N_(2)O_(5) rarr N_(2)O_(4) + 1//2O_(2) . After 20 min the volume of O_(2) profuced is 10 mL and at the end of the reaction 40 mL . The rate constant is equal to

The half life of decompoistion of N_(2)O_(5) is a first order reaction represented by N_(2)O_(5)rarrN_(2)O_(4)+1//2O_(2) After 15 min the volume of O_(2) profuced is 9ml and at the end of the reaction 35ml . The rate constant is equal to

1L of CO_(2) is passed over hot coke . then volume after complete reaction is ? when the vol of reaction mix becomes 1.4L

CENGAGE CHEMISTRY-CHEMICAL KINETICS-Exercises Single Correct
  1. The half-life periof of the reaction in the above question is

    Text Solution

    |

  2. The reaction kinetics can be studied by

    Text Solution

    |

  3. Half life id independent of the concentration of A. After 10 mi n volu...

    Text Solution

    |

  4. Ararr Product, [A](0) = 2M. After 10 min reaction is 10% completed. If...

    Text Solution

    |

  5. Graph between log k and 1//T [k rate constant (s^(-1)) and T and the t...

    Text Solution

    |

  6. The rate of a chemical reaction generally increases rapidly even for s...

    Text Solution

    |

  7. Rate is expressed in mol L^(-1) min^(-1). In the above reaction, the...

    Text Solution

    |

  8. Rate constant k = 1.2 xx 10^(3) mol^(-1) L s^(-1) and E(a) = 2.0 xx 10...

    Text Solution

    |

  9. The rate constant of a reaction is 0.0693 min^(-1). Starting with 10 m...

    Text Solution

    |

  10. The graph between concentration (X) of the Product and time of the rea...

    Text Solution

    |

  11. Following is the graph between log T(50) and log a (a = initial concen...

    Text Solution

    |

  12. The half life of radioactive element is 20 min. The time interval betw...

    Text Solution

    |

  13. Which of the following reaction is not of the first order ?

    Text Solution

    |

  14. For the reaction X+3Y rarrZ, which form of differential rate law is in...

    Text Solution

    |

  15. 60% of a first order reaction was completed in 60 min. The time taken ...

    Text Solution

    |

  16. 70% of a first order reaction was completed in 70 min. What is the hal...

    Text Solution

    |

  17. 80% of a fisrt order reaction was completed in 70 min. How much it wil...

    Text Solution

    |

  18. 90% of a first order reaction was completed in 100 min. How much time ...

    Text Solution

    |

  19. 90% of a first order reaction was completed in 100 min.What is the hal...

    Text Solution

    |

  20. The hydrolyiss of ester in alkaline medium is a

    Text Solution

    |