Home
Class 12
CHEMISTRY
In a certain reaction, 10% of the reacta...

In a certain reaction, `10%` of the reactant decomposes in one hour, `20%` in two hours, `30%` in theee hours, and so on. The dimenison of the velocity constant (rate constant) are

A

`hr^(-1)`

B

`Mol L^(-1) hr^(-1)`

C

`L mol^(-1) s^(-1)`

D

`Mol s^(-1)`

Text Solution

Verified by Experts

The correct Answer is:
B

form the question, it is clear `t_(1//2) prop a`. Hence, zero order reaction. So, dimenison of `k = mol L^(-1) hr^(-1)`.
For zero order: `t = (x)/(k) or k = (x)/(t)`
If `t = t_(10%) = 10 min, x = 10`,
Then, `k = (10)/(10) = 1 mol L^(-1) t^(-1)`.
If `t = t_(20%) = 20 min, x = 20`,
Then, `k = (20)/(20) = 1 mol L^(-1) t^(-1)`.
ismilarly, for `30%` and so on. Thus, reaction is of zero order.
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL KINETICS

    CENGAGE CHEMISTRY|Exercise Exercises Assertion-Reasoning|22 Videos
  • CHEMICAL KINETICS

    CENGAGE CHEMISTRY|Exercise Exercises Integer|15 Videos
  • CHEMICAL KINETICS

    CENGAGE CHEMISTRY|Exercise Exercises Multiple Correct|34 Videos
  • CARBOXYLIC ACIDS AND THEIR DERIVATIVES

    CENGAGE CHEMISTRY|Exercise Exercises Archives (Analytical And Descriptive)|34 Videos
  • COORDINATION COMPOUNDS

    CENGAGE CHEMISTRY|Exercise Archives Subjective|18 Videos

Similar Questions

Explore conceptually related problems

For a certain readction, 10% of the reactant decomposes in one hour, 20% in two hours and 30% in three hours. The unit of rate constant will be

Some graph are sketched for the reactant decomposes in one hour, 20% in two hours, 30% in three hours and so on. The dimensions of the rate constant is: The order of reaction are respectively.

" In a certain reaction "10%" of reactant decomposes in "1" hour,"20%" in two hours and "30%" in three hours on starting with a particular concentration of reactant.The order of reaction is "

CENGAGE CHEMISTRY-CHEMICAL KINETICS-Exercises Single Correct
  1. The activation energy of reactant molecules in a reaction depends upon

    Text Solution

    |

  2. The dissociation of nitrogen pentaoxide is a first order reaction. In ...

    Text Solution

    |

  3. In a certain reaction, 10% of the reactant decomposes in one hour, 20%...

    Text Solution

    |

  4. The decompoistion of H(2)O(2) can be followed by titration with KMnO(4...

    Text Solution

    |

  5. The half life of decompoistion of N(2)O(5) is a first order reaction r...

    Text Solution

    |

  6. The rate constant of a reactant is 1.5 xx 10^(-3) at 25^(@)C and 2.1 x...

    Text Solution

    |

  7. In the reaction A + B rarr C+D, the concentration of A and B are equal...

    Text Solution

    |

  8. If a graph is plotted between log (a-x) and t, the slope of the straig...

    Text Solution

    |

  9. In the Wilhelmey equation of a first order reaction c(t) = c(0)e^(-kt)...

    Text Solution

    |

  10. The mechanism of the reaction 2NO + O(2) rarr 2NO(2) is NO + NO un...

    Text Solution

    |

  11. True statement is

    Text Solution

    |

  12. In a second order reaction, 20% of a substance is dissociated in 40 mi...

    Text Solution

    |

  13. t(1//2) = constant confirms the first order of the reaction as one a^(...

    Text Solution

    |

  14. Collision theory is applicable to

    Text Solution

    |

  15. The wrong statement is

    Text Solution

    |

  16. Which of the following will react at the highest rate ?

    Text Solution

    |

  17. For a reaction, the rate constant is expressed as k = Ae^(-40000//T). ...

    Text Solution

    |

  18. A reaction takes place in theee steps: the rate constant are k(1), k(2...

    Text Solution

    |

  19. A reaction rate constant is given by k = 1.2 xx 10^(14) e^((-2500)/(...

    Text Solution

    |

  20. For the reaction 2NO(g) + H(2)(g) rarr N(2)O(g) + H(2)O(g), at 900 K f...

    Text Solution

    |