Home
Class 12
CHEMISTRY
The half life period for catalytic decom...

The half life period for catalytic decomposition of `AB_(3)` at 50 mm is found to be 4 hrs and at 100 mm it in 2 hrs. The order of reaction is :

A

`3`

B

`1`

C

`2`

D

`0`

Text Solution

Verified by Experts

The correct Answer is:
C

When initial pressure of `AB_(3) = 100 mm`
`t_(1//2) = 2 hr`.
It means when concentration is doubled, half life is halved. So, it is a second order reaction.
For second order reaction: `t_(1//2) prop (a)^(-1)`
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL KINETICS

    CENGAGE CHEMISTRY|Exercise Exercises Assertion-Reasoning|22 Videos
  • CHEMICAL KINETICS

    CENGAGE CHEMISTRY|Exercise Exercises Integer|15 Videos
  • CHEMICAL KINETICS

    CENGAGE CHEMISTRY|Exercise Exercises Multiple Correct|34 Videos
  • CARBOXYLIC ACIDS AND THEIR DERIVATIVES

    CENGAGE CHEMISTRY|Exercise Exercises Archives (Analytical And Descriptive)|34 Videos
  • COORDINATION COMPOUNDS

    CENGAGE CHEMISTRY|Exercise Archives Subjective|18 Videos

Similar Questions

Explore conceptually related problems

The half life period for catalytic decomposition of XY_3 at 100 mm is found to be 8 hrs and at 200 mm it is 4 hrs. The order of reaction is

The half -lie period for the decomposition of AB_(2)(g) at 100mm pressure is 10min and at 200mm pressure is 5 min, the order of reaction is

The half-life period of any first order reaction:

CENGAGE CHEMISTRY-CHEMICAL KINETICS-Exercises Single Correct
  1. The activation energy for a hypothetical reaction A rarr X is 12.49 kc...

    Text Solution

    |

  2. How will the rate of reaction 2SO(2)(g) + O(2)(g) rarr 2SO(3)(g) cha...

    Text Solution

    |

  3. The half life period for catalytic decomposition of AB(3) at 50 mm is ...

    Text Solution

    |

  4. The hydrolyiss of an ester was carried out with 0.1 M H(2)SO(4) and 0....

    Text Solution

    |

  5. For a zero order reaction, the plot of concentration of a reactant vs ...

    Text Solution

    |

  6. In a certain gaseous reaction between A and B, A + 3B rarr AB(3). The ...

    Text Solution

    |

  7. In the presence of acid, the initial concentration of cane sugar was r...

    Text Solution

    |

  8. For an elementary reaction , X(g)toY(g)+Z(g) the half life period is...

    Text Solution

    |

  9. If a is the initial concentration of reaction, then the half-life peri...

    Text Solution

    |

  10. The rate constant of forward and backward reactions for certain hypoth...

    Text Solution

    |

  11. The activation energy for most of the reaction is approximately 50 kJ ...

    Text Solution

    |

  12. Which of the following theory is not related to the chemical kinetics?

    Text Solution

    |

  13. When the concentration of a reactant in reaction A rarr B is increased...

    Text Solution

    |

  14. Phosphrous undergoes slow combustion and glows in dark. The precess is...

    Text Solution

    |

  15. The rate law for the reaction RCl + NaOH(aq) rarr ROH + NaCl is give...

    Text Solution

    |

  16. The rate of reaction between A and B increases by a factor of 100, whe...

    Text Solution

    |

  17. The efficiently of an enzyme in catalyzing a reaction is due to its ca...

    Text Solution

    |

  18. When KClO(3) is heated, it decomposes into KCl and O(2). If some MnO(2...

    Text Solution

    |

  19. For a chemical reaction A rarr B, it is found that the rate of reacti...

    Text Solution

    |

  20. The reaction 2N(2)O(5)(g) rarr 4NO(2)(g) is first order w.r.t. N(2)O(5...

    Text Solution

    |