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For the reaction NO(2)+COrarrCO(2)+NO, t...

For the reaction `NO_(2)+COrarrCO_(2)+NO`, the experimental rate expresison is `-dc//dt = k[NO_(2)]^(2)`. Find the number of molecules of `CO` involved in the slowest step.

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To solve the problem, we need to analyze the given reaction and the rate expression provided. Here’s a step-by-step breakdown of the solution: ### Step 1: Understand the Reaction The reaction given is: \[ \text{NO}_2 + \text{CO} \rightarrow \text{CO}_2 + \text{NO} \] ### Step 2: Identify the Rate Expression The experimental rate expression provided is: \[ -\frac{d[\text{C}]}{dt} = k[\text{NO}_2]^2 \] This indicates that the rate of the reaction depends on the concentration of \(\text{NO}_2\) raised to the power of 2. ### Step 3: Determine the Rate-Determining Step In chemical kinetics, the rate-determining step (RDS) is the slowest step in a reaction mechanism that dictates the overall rate of the reaction. Since the rate expression is dependent only on \([\text{NO}_2]\), this suggests that the slowest step involves \(\text{NO}_2\) and does not involve \(\text{CO}\). ### Step 4: Analyze the Involvement of CO The question asks for the number of molecules of \(\text{CO}\) involved in the slowest step. Since the rate expression does not include \([\text{CO}]\), it implies that \(\text{CO}\) does not participate in the rate-determining step. ### Step 5: Conclude the Number of CO Molecules Since \(\text{CO}\) is not involved in the slowest step, the number of molecules of \(\text{CO}\) in the slowest step is: \[ \text{Number of CO molecules} = 0 \] ### Final Answer The number of molecules of \(\text{CO}\) involved in the slowest step is **0**. ---
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