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The hybrid states of central atom in dib...

The hybrid states of central atom in diborane, diamond and graphite are respectively :-

A

`sp^(2),sp^(3),sp^(2)`

B

`sp^(3),sp^(3),sp^(2)`

C

`sp^(3),sp^(3),sp^(2)`

D

`sp,sp^(2),sp^(3)`

Text Solution

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The correct Answer is:
To determine the hybrid states of the central atom in diborane, diamond, and graphite, we will analyze each compound step by step. ### Step 1: Analyze Diborane (B2H6) 1. **Identify the Structure**: Diborane has the formula B2H6. It consists of two boron atoms and six hydrogen atoms. 2. **Bonding Type**: The bonding in diborane is characterized by 3-center 2-electron bonds. This means that two boron atoms share electrons with three hydrogen atoms in a unique bonding arrangement. 3. **Geometry**: The geometry around each boron atom is tetrahedral due to the presence of four bonding pairs (two B-H bonds and two bridge bonds). 4. **Hybridization**: For tetrahedral geometry, the hybridization state is sp3. ### Conclusion for Diborane: - **Hybridization**: sp3 ### Step 2: Analyze Diamond 1. **Identify the Structure**: Diamond is an allotrope of carbon. 2. **Bonding Type**: In diamond, each carbon atom is bonded to four other carbon atoms. 3. **Geometry**: The arrangement of carbon atoms in diamond is also tetrahedral. 4. **Hybridization**: Similar to diborane, the hybridization for tetrahedral geometry is sp3. ### Conclusion for Diamond: - **Hybridization**: sp3 ### Step 3: Analyze Graphite 1. **Identify the Structure**: Graphite consists of layers of hexagonal rings made up of carbon atoms. 2. **Bonding Type**: Each carbon atom in graphite is bonded to three other carbon atoms in the same plane, forming a hexagonal structure. 3. **Geometry**: The geometry around each carbon atom in the hexagonal plane is trigonal planar. 4. **Hybridization**: For trigonal planar geometry, the hybridization state is sp2. ### Conclusion for Graphite: - **Hybridization**: sp2 ### Final Summary: - **Diborane**: sp3 - **Diamond**: sp3 - **Graphite**: sp2 ### Final Answer: The hybrid states of the central atom in diborane, diamond, and graphite are respectively: **sp3, sp3, sp2**. ---
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