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Arrange the following ligands in the dec...

Arrange the following ligands in the decreasing order of priority.
a. i.`-OH` , ii. `-COOH`
iii `-CH_(2)OH` , iv.`CH(OH)CH_(3)`
b. i. `-NH_(2)` ii. `-C-=N`
iii. `-NO_(2)` iv. `-CH_(2)NH_(2)`

Text Solution

Verified by Experts

a.(i)`gt` (ii) `gt` (iv)`gt` (iii) `(-OH gt -COOH gt-CH(OH)CH_(3) gt -CH_(2)OH)`
b. `(iii) gt (i) gt (iv) (-NO_(2) gt -NH_(2) gt -C-=N`
c. `(ii) gt (i)` ,

In cyclohexy, `(-CH)` is joined to two `(CH_(2))` groups and is further joined to another ring `C` atom.
In (i), `(-CH)` is joined to two `(CH_(3))` groups each having three `H` atoms.
d. (ii) `gt` (i)
Phenyl `C` is doubly bonded and counted as attached to three `C` atoms.
e. `(i) gt (ii) ["Phenyl" gt -C(CH_(3))_(3)]`
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