`[Fe(CN)_(6)]^(3-)` एक दुर्बल अनुचुम्बकीय (paramagnetic) है जबकि `[Fe(CN)_(6)]^(4-)` प्रतिचुम्बकीय (diamagnetic) है, क्यों ?

Explain the following:- Ferri cyanide complex [Fe(CN)_6]^(3-) is weakly paramagnetic whereas Ferrocyanide complex [Fe(CN)_6]^(4-) is diamagnetic.

Assertion : [Fe(CN)_6]^(3-) is weakly paramagnetic while [Fe(CN)_6]^(4-) is diamagnetic. Reason : [Fe(CN)_6]^(3-) has +3 oxidation state while [Fe(CN)_6]^(4-) has +2 oxidation state.

How would you account for the following : [Fe(CN)_6]^(3-) is weakly paramagnetic while [Fe(CN)_6]^(4-) is diamagnetic

Assertion: [Fe(CN)_6]^(3-) is weakly paramagnetic while [Fe(CN)_6]^(4-) is diamagnetic Reason: Both [Fe(CN)_6]^(3-) and [Fe(CN)_6]^(4-) involve d^2sp^3 hybridisation. In [Fe(CN)_6]^(3-) singly occupied d-orbital is available but in [Fe(CN)_6]^(4-) paired electrons are present

[Fe(H_(2)O)_(6)]^(3+) is strongly paramagnetic whereas [Fe(CN)_(6)]^(3-) is weakly paramagnetic Explain.

[Fe(H_(2)O)_(6)]^(3+) is strongly paramagnetic whereas [Fe(CN)_(6)]^(3-) is weakly paramagnetic. Explain.