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8:8 coordination of CsCl is found to cha...

8:8 coordination of CsCl is found to change into 6:6 coordination :

A

high temperature

B

high pressure

C

high temperature and high pressure

D

low temperature and low pressure.

Text Solution

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The correct Answer is:
B

Increase of pressure increases coordination number. Hence, by applying high pressure , NaCl type crystal can be changed into CsCl type crystal
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Statement : 8:8 co - ordination of CsCl at low temperature changes to 6:6 co - ordinationat 760K . Explanation : Temperature also infuences the strutures of solids.

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A : In NaCl coordination number of Cl^(-) ion is 6 but in CsCl coordination number of Cl^(-) ion is 8. R : Ionic radii changes with type of lattice.

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NCERT FINGERTIPS-THE SOLID STATE -Number Of Atoms In Unit Cell And Close Packed Structures
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  9. How many chloride ions are there around sodium ion in sodium chloride ...

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  10. In NaCl structure , all the :

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  11. 8:8 coordination of CsCl is found to change into 6:6 coordination :

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  12. In CsCI lattice the coordination number of Cs ion is

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  13. Which is /are correct statement about zinc blende structure ?

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  14. The unit cell shown in the figure belongs to

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  15. The coordination number of Y will be

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  16. Which of the following about the above structure is not correct ?

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  17. In CaF(2) type (fluorite structure) Ca^(2+) ions form W structure and ...

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