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For a reaction, 2NO + 2H(2) to N(2) + 2H...

For a reaction, `2NO + 2H_(2) to N_(2) + 2H_(2) O`, the possible mechanism is
`NO hArr N_(2)O_(2)`
`N_(2)O_(2) + H_(2) overset("Slow")(to) N_(2)O + H_(2) O`
`N_(2) O + H_(2) O overset("fast")(to) N_(2) + H_(2) O`
What is the rate law and order of the reaction?

A

Rate = `[N_(2)O_(2)]`, order = 1

B

Rate = `[N_(2)O_(2)][H_(2)]`, order = 2

C

Rate = `[N_(2)O_(2)]^(2)` order = 2

D

Rate = `[N_(2)O_(2)]^(2) [H_(2)]`, order = 3

Text Solution

AI Generated Solution

The correct Answer is:
To determine the rate law and order of the reaction given the mechanism, we will follow these steps: ### Step 1: Identify the Rate-Determining Step The rate of a reaction is determined by its slowest step, known as the rate-determining step. In this case, the slow step is: \[ N_2O_2 + H_2 \overset{\text{Slow}}{\to} N_2O + H_2O \] ### Step 2: Write the Rate Law The rate law can be expressed based on the reactants involved in the rate-determining step. For the slow step, the rate law can be written as: \[ \text{Rate} = k [N_2O_2]^1 [H_2]^1 \] Here, \( k \) is the rate constant, and the exponents correspond to the stoichiometric coefficients of the reactants in the rate-determining step. ### Step 3: Simplify the Rate Law Since the exponents are both 1, we can simplify the rate law to: \[ \text{Rate} = k [N_2O_2] [H_2] \] ### Step 4: Determine the Overall Order of the Reaction The overall order of the reaction is the sum of the exponents in the rate law. In this case: - The exponent for \( [N_2O_2] \) is 1. - The exponent for \( [H_2] \) is 1. Thus, the overall order is: \[ 1 + 1 = 2 \] ### Final Answer - **Rate Law**: \( \text{Rate} = k [N_2O_2] [H_2] \) - **Order of the Reaction**: 2 ---

To determine the rate law and order of the reaction given the mechanism, we will follow these steps: ### Step 1: Identify the Rate-Determining Step The rate of a reaction is determined by its slowest step, known as the rate-determining step. In this case, the slow step is: \[ N_2O_2 + H_2 \overset{\text{Slow}}{\to} N_2O + H_2O \] ### Step 2: Write the Rate Law The rate law can be expressed based on the reactants involved in the rate-determining step. For the slow step, the rate law can be written as: ...
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