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In the metallurgy of aluminium,...

In the metallurgy of aluminium,

A

`Al^(3+)` is oxidised to `Al_((s))`

B

graphite anode is oxidised to carbon monoxide and carbon dioxide.

C

oxidation state of oxygen changes in the reaction at anode

D

oxidation state of oxygen change in the overall reaction involved in the process.

Text Solution

Verified by Experts

The correct Answer is:
B

The oxidation state of O does not change in either the reaction occurring at the anode or the overall reaction as shown below :
At anode :
`C + O^(2-) to overset(2+)Coverset(2-)O+2e^(-) , 2overset(2-)O to overset(4+)C overset(2-)O_(2)+4e^(-)`
At cathode : `Al^(3+) +3e^(-) to Al`
Overall reaction : `2overset(3+)(A_(2))overset(2-)(O_(3)) + 3C to 4Al + 3overset(2+)Coverset(2-)O_(2)`
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