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The reactions of CI(2) gas with cold-dil...

The reactions of `CI_(2)` gas with cold-dilute and hot-concentrated NaOH in water give sodium salts of two different oxioacids of chlorine, P and Q, respectively. The `CI_(2)` gas reacts with `SO_(2)` gas, in presence of charocal, to give a product R reacts with white phosphorus to give a compound S. On hydrolysis, S gives an oxoacid of phosphorus.
R, S and T, respectively, are

A

`SO_(2)Cl_(2), PCl_(5) and H_(3)PO_(4)`

B

`SO_(2)Cl_(2), PCl_(3) and H_(3)PO_(3)`

C

`SOCl_(2), PCl_(3) and H_(3)PO_(2)`

D

`SOCl_(2), PCl_(5) and H_(3)PO_(4)`

Text Solution

Verified by Experts

The correct Answer is:
A
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The reactions of CI_(2) gas with cold-dilute and hot-concentrated NaOH in water give sodium salts of two different oxioacids of chlorine, P and Q, respectively. The CI_(2) gas reacts with SO_(2) gas, in presence of charocal, to give a product R reacts with white phosphorus to give a compound S. On hydrolysis, S gives an oxoacid of phosphorus. P and Q, respectively, are the sodium salts of