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The reactions of CI(2) gas with cold-dil...

The reactions of `CI_(2)` gas with cold-dilute and hot-concentrated NaOH in water give sodium salts of two different oxioacids of chlorine, P and Q, respectively. The `CI_(2)` gas reacts with `SO_(2)` gas, in presence of charocal, to give a product R reacts with white phosphorus to give a compound S. On hydrolysis, S gives an oxoacid of phosphorus.
P and Q, respectively, are the sodium salts of

A

hypochlorous and chloric acids

B

hypochlorous and chlorous acids

C

chloric and perchloric acids

D

chloric and hypochlorous acids.

Text Solution

Verified by Experts

The correct Answer is:
A
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The reactions of CI_(2) gas with cold-dilute and hot-concentrated NaOH in water give sodium salts of two different oxioacids of chlorine, P and Q, respectively. The CI_(2) gas reacts with SO_(2) gas, in presence of charocal, to give a product R reacts with white phosphorus to give a compound S. On hydrolysis, S gives an oxoacid of phosphorus. R, S and T, respectively, are