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If M is the element of actinoid series, ...

If M is the element of actinoid series, the degree of complex formation decrease in the order

A

`M^(4+) gt M^(3+) gtMO_2^(2+) gt MO_2^(+)`

B

`MO_2^(+) gt MO_2^(2+) gt M^(3+) gt M^(4+)`

C

`M^(4+) gt MO_2^(2+) gt M^(3+) gt MO_2^(+)`

D

`MO_2^(2+) lt MO_2^(+) lt M^(3+) gt M^(3+)`

Text Solution

Verified by Experts

The correct Answer is:
C

The higher the charge on the metal ion, smaller is the ionic size and more is the complex forming ability. Thus, the degree fo complex formation decreases in the order `M^(4+) gt MO_2^(2+) gt M^(3+) gt MO_2^(+)`
The higher tendecy of complex formation of `MO_2^(2+)` as compared of `M^(3+)` is due to high concentration of charge on metal atom M in `MO_2^(2+)`.
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