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Which of the following complex will give...

Which of the following complex will give white ppt. with `BaCl_(2)` solution ?

A

`[Co(NH_(3))_(5) SO_(4)]Br`

B

`[Co(NH_(3))_(5)Br]SO_(4)`

C

`[Co(NH_(3))_(4) (SO_(4))_(2) ]Br`

D

`[Co(NH_(3))_(4) Br(SO_(4))]`

Text Solution

Verified by Experts

The correct Answer is:
B
`[Co(NH_(3))_(5)Br]SO_(4) hArr [Co(NH_(3))_(5) Br]^(2+) + SO_(4)^(2-) `
`SO_(4)^(2-) + BaCl_(2) to underset("white ppt.")(BaSO_(4)) + 2Cl^(-)`
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