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Which of the following sets of examples ...

Which of the following sets of examples and geometry of the compounds is not correct ?

A

Octahedral - `[Co(NH_(3))_(6)]^(3+) , [Fe(CN)_(6)]^(3-)`

B

Square planar - `[Ni(CN)_(4)]^(2-) , [Cu(NH_(3))_(4)]^(2+)`

C

Tetrahedral - `[Ni(CO)_(4)] , [ZnCl_(4)]^(2-)`

D

Trigonal bipyramidal - `[Fe(NH_(3))_(6)]^(2+) , [CuCl_(4)]^(2-)`

Text Solution

Verified by Experts

The correct Answer is:
D

`[CuCl_(4)]^(2-) ` : Tetrahedral
`[Fe(NH_(3))_(6)]^(2+) ` : Octahedral
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NCERT FINGERTIPS-COORDINATION COMPOUNDS -Bonding In Coordination Compounds
  1. The anion [Co(C(2)O(4))(3)]^(3-) involves hybridization

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  2. Which of the following sets of examples and geometry of the compounds ...

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  3. Match the examples given in column I with the shapes of the compounds ...

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  4. Which of the following is correct ?

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  5. Mark the incorrect statement .

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  6. Which of the following facts about the complex [Cr(NH(3))(6)]Cl(3) is...

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  7. Which of the following molecules has a regular tetrahedral shape?

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  8. Mark the correct statements regarding the geometry of complex ions . ...

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  9. Which of the following complex ion does not have 'd'-electrons in the ...

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  10. Give reason for the statement [Ni(CN)(4)]^(2-) is diamagnetic while [N...

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  11. The lowest value of paramagnetism is shown by

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  12. Explain the following: (i) All the octahedral complexes of Ni^(2+)...

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  13. Deduce the structures of [NiCl(4)]^(2-) and [Ni (CN)(4)]^(2-) consider...

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  14. Which of the following has largest paramagnetism ?

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  15. Using valence bond theory , the complex [Cr(H(2)O)(6)]^(3+) can be des...

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  16. Which of the following descriptions about [FeCl(6)]^(4-) is correct ab...

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  17. When excess of ammonia is added to CuSO4 solution, the deep blue colou...

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  18. Pick out the correct statement with respect to [Mn(CN)(6)]^(3-):

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  19. Among the following the compound that is both paramagnetic and coloure...

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  20. The spin only magnetic moment value of Cr(CO)(6) is

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