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[Cr(H2 O)6]Cl3 (at no. of Cr = 24) has a...

`[Cr(H_2 O)_6]Cl_3` (at no. of Cr = 24) has a magnetic moment of `3.83 B.M`. The correct distribution of `3d` electrons the chromium of the complex.

A

`3d_(xy)^(1) , 3d_(yz)^(1) , 3 d_(zx)^(1)`

B

`3d_(xy)^(1) , 3d_(yz)^(1) , 3d_(z^(2))^(1)`

C

`3d_((x^(2) - y^(2)))^(1) , 3d_(z^(2))^(1) , 3d_(xz)^(1)`

D

`3d_(xy)^(1) , 3d_((x^(2)- y^(2)))^(1) , 3d_(yz)^(1)`

Text Solution

Verified by Experts

The correct Answer is:
A

Magnetic moment indicates that there are three unpaired electrons present in chromium . These must be present in lower energy orbitals which are `3d_(xy) , 3d_(yz) ` and `3d_(xz)`
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