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Assertion : [Co(NH(3))(5)Br]SO(4) gives ...

Assertion : `[Co(NH_(3))_(5)Br]SO_(4)` gives white precipitate with barium chloride .
Reason : The complex `[Co(NH_(3))_(5)Br]SO_(4)` dissociates in the solution to give `Br^(-)` and `SO_(4)^(2-)`.

A

If both Assertion and reason are true and reason is the correct explanation of assertion

B

If both assertion and reason are true but reason is not the correct explanation of assertion

C

If assertion is true but reason is false

D

if both assertion and reason are false

Text Solution

Verified by Experts

The correct Answer is:
C

The complex `[Co(NH_(3))_(5) Br]SO_(4)` dissociates to give `[Co(NH_(3))_(5)Br]^(2-)` and `SO_(4)^(2-)` ions . `SO_(4)^(2-)` ion reacts with barium chloride to give white ppt. of `BaSO_(4)`,
`SO_(4)^(2-) + BaCl_(2) to BaSO_(4) + 2 Cl^(-)`
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Knowledge Check

  • Aqueous solution of [Co(H_(2)O)_(5)SO_(4)]Cl gives precipitate with

    A
    `BaCl_(2(aq))`
    B
    `AgNO_(3 (aq))`
    C
    both 1 and 2
    D
    neither 1 nor 2
  • The complex [Co(NH_(3))_(5)Br]SO_(4) will give white ppt with

    A
    `PbCl_(2)`
    B
    `AgNO_(3)`
    C
    KI
    D
    None of these
  • [Co(NH_(3))_(5)NO_(2)]SO_(4) shows

    A
    Ionisation isomerism
    B
    Coordination isomerism
    C
    Linkage isomerism
    D
    Position isomerism
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