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Which one of the following is not the co...

Which one of the following is not the correct order of boiling points of alkyl `//` aryl halides ?

A

`CHCl_3gtCH_2Cl_2`

B

`CH_3(CH_2)_3ClgtCH_3(CH_2)_2Cl`

C

`(CH_3)_3CClgt(CH_3)_2CHCH_2Cl`

D

`CH_3(CH_2)_3ClgtCH_2CH_2CHClCH_3`

Text Solution

Verified by Experts

The correct Answer is:
C
`(CH_3)_3C Cl gt (CH_3)_2CHCH_2Cl` is not correct as boiling point of `(CH_3)_3 C Cl` is smaller than `(CH_3)_2CHCH_2Cl`. It is due to large surface area and shorter alkyl chain.
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