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Tertiary alkyl halide are practially in...

Tertiary alkyl halide are practially inert to substitution by `SN^(2)` mechanism because of-

A

the carbocation formed is unstable

B

there is steric hindrace

C

there is inductive effect

D

the rate of reaction is faster is `S_(N^2)` mechanism.

Text Solution

Verified by Experts

The correct Answer is:
B

In tertiary alkyl halides steric hindrance does not allow subsitution by `S_(N^2)` mechanism in which the numbleophile attacks on the carbon atom and the reaction takes place in single step.
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SN^(1) and SN^(2) mechanisms

NCERT FINGERTIPS-HALOALKANES AND HALOARENES-Chemical Reactions
  1. Which of the following statement is not correct about SN^2 reactions o...

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  2. In the reaction given below: Which of the following statements is...

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  3. Tertiary alkyl halide are practially inert to substitution by SN^(2) ...

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  4. Among the choices of alkyl bromide , the least reactive bromide in a ...

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  5. Arrange the following compounds in order of their reactivity towards S...

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  6. Which of the following haloalkanes is most reactive?

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  7. Which of the following reactions does not take place?

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  8. Consider the following bromides: The correct order of S(N^1) reac...

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  9. Which of the following statement regarding S(N)1 reaction shown by alk...

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  10. Consider the following reaction: C6H5-underset(H)underset(|)overset(...

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  11. Which one of the following chlorohydrocarbons readily undergoes solvol...

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  12. Which of the following is the most reactive towards nucleophilic subst...

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  13. SN^1 reaction is fastest in

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  14. Which of the following alkyl halides is hydrolysed by S(N^(1)) mechani...

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  15. Which of the following will give enantiomeric pair on reaction with wa...

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  16. Which of the following is most reactive towards aqueous NaOH?

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  17. In the following pairs of halogen compounds, which compounds undergoes...

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  18. Which of the following haloalkanes reacts with aqueous KOH most easily...

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  19. Which alkyl halide exhibits complete racemisation in S(N^1) reaction?

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  20. The order of reactivity of various alkyl halides towards nucleophilic ...

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