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The electronic configuration of carbon i...

The electronic configuration of carbon is `1s^(2) 2s^(2) 2p^(2)`.
There are 12 electrons in `C_(2)` . The correct electronic configuration of `C_(2)` molecule is

A

`(sigma1s^(2))(sigma^(**)1s^(2))(sigma2s^(2))(sigma^(**)2s^(2))(sigma2p_(z)^(2))(pi2p_(x)^(2))`

B

`(sigma1s^(2))(sigma^(**)1s^(2))(sigma2s^(2))(sigma^(**)2s^(2))(pi2p_(x)^(2)=pi2p_(y)^(2))`

C

`(sigma1s^(2))(sigma^(**)1s^(2))(sigma2s^(2))(sigma^(**)2s^(2))(sigma2p_(z)^(2))(pi2p_(x)^(1)=pi2p_(y)^(1))`

D

`(sigma1s^(2))(sigma^(**)1s^(2))(sigma2s^(2))(sigma^(**)2s^(2))(pi2p_(x)^(2)=pi2p_(y)^(1))`

Text Solution

Verified by Experts

The correct Answer is:
B

For atoms like nitrogen and below N in atomic number have higher energy for `p_(z) `- orbital, hence the configuration for `C_(2)` molecule is
`(sigma 1s^(2))(sigma^(**)1s^(2))(sigma2s^(2))(sigma^(**)2s^(2))(pi 2p_(x)^(2)=pi2p_(y)^(2))`.
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