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The oxidation state of S in H(2)S(2)O(8)...

The oxidation state of `S` in `H_(2)S_(2)O_(8)` is

A

`+6`

B

`+7`

C

`+8`

D

0

Text Solution

Verified by Experts

The correct Answer is:
A

`H_(2)S_(2)O_(8)`
`H-O-underset(O)underset(||)overset(O)overset(||)S-O-O-underset(O)underset(||)overset(O)overset(||)S-O-H`
Two oxygen atoms are involved in peroxide linkage, hence oxidation number will be -1 (each).
`H_(2)S_(2)O_(8)=underset(H)(2(+1))+underset(S)(2(x))+underset(O-O)(2(-1))+underset(O)(6(-2))=0`
`x=+6`
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