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Which will be the value of x, y and z in...

Which will be the value of x, y and z in the following equaton.
`xI_(2)+yOH^(-)rarrIO_(3)^(-)+zI+3H_(2)O`

A

`{:(x,y,z),(6,3,5):}`

B

`{:(x,y,z),(3,2,3):}`

C

`{:(x,y,z),(3,6,5):}`

D

`{:(x,y,z),(3,3,3):}`

Text Solution

Verified by Experts

The correct Answer is:
C

`I_(2)+OH^(-)rarr IO_(3)^(-)+I^(-)+H_(2)O`
Oxidation half : `I_(2)+OH^(-)rarr IO_(3)^(-)+H_(2)O`
Reduction half : `I_(2)rarr I^(-)`
Oxidation half-
Adding `OH^(-), I_(2)+12OH^(-)rarr 2IO_(3)^(-)+6H_(2)O`
Adding electrons :
`I_(2)+12OH^(-)rarr 2I_(3)^(-)+6H_(2)O+10e^(-)`
Reduction half -
`I_(2)+2e^(-)rarr 2I^(-)`
Balancing `e^(-), I_(2)+12OH^(-)rarr 2IO_(3)^(-)+6H_(2)O+10e^(-)`
`I_(2)+2e rarr 2I^(-)] xx 5`
Adding both reactions
`6I_(2)+12OH^(-)rarr 2IO_(3)^(-)+10I^(-)+6H_(2)O`
Dividing by 2,
`3I_(2)+6OH^(-)rarr IO_(3)^(-)+5I^(-)+3H_(2)O`
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