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What is the trend of boiling points of h...

What is the trend of boiling points of hydrides of N, O and F ?

A

Due to lower molecular masses `NH_(3), H_(2)O` and HF have lower boiling points than those of the subsequent group member hydrides.

B

Due to higher electronegativity of N, O and F, `NH_(3), H_(2)O` and HF show hydrogen bonding and hence higher boiling points than the hydrides of their subsequent group members.

C

There is no regular trend in the boiling points of hydrides.

D

Due to higher oxidation states of N, O and F, the boiling points of `NH_(3), H_(2)O` and HF are higher than the hydrides of their subsequent group members.

Text Solution

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The correct Answer is:
B

Due to higher electronegativity, the extent of hydrogen bonding is quite appreaciable.
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Fifth group elements form hydrides to type AH_(3) . The hydrides have a lone pair of electrons. The hydries are reducing in nature and the reducing power is related to the stability of A-H bonds. The hydrides are covalent and low boiling. Their boiling points depends on their ability to from hydrogen bond and their molecular size which decide the intermolcular forces in the hydrides . The boiling points of the hydrides of V-group elements are in the order :