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Lithium is the strongest reducing agent ...

Lithium is the strongest reducing agent though it has highest ionisation enegy in its group. Which of the followinng factors is responsible for making Li the strongest reducing agent?

A

Large heat of atomisation

B

Smaller size

C

Large sublimation energy

D

Large amount of hydration enthalpy

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The correct Answer is:
D

Large amount of hydration energy makes it strongest reducing agent inspite of its highest ionisation enthalpy.
`M_((s)) underset("energy")overset("Sublimation")to M_((g)) underset("Energy")overset("Ionisation")to M_((g))^(+) underset("energy")overset("Hydration")to M_((aq))^(+)`
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NCERT FINGERTIPS-THE S-BLOCK ELEMENTS-Assertion And Reason
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  2. Assertion: Elements of group 1 are called 'alkali metals'. Reason: A...

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  3. Assertion: Lithium resembles magnesium diagonally placed in next group...

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  4. Assertion: Alkali metals are obtained by electrolysis of molten salt a...

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  5. Assertion: Lithium salts are mostly hydrated. Reason: The hydration ...

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  6. Assertion: The melting and boiling points of the alkali metals are low...

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  7. Assertion: Lithium fluoride is most covalent in nature. Reason: Smal...

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  8. Assertion: The carbonate of lithium decomposes easily on heating. Re...

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  9. Assertion : Super-oxides of alkali metals are para-magnetic. Reason ...

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  10. Assertion: Be and Mg do not impat characteristic colour to the flame. ...

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  11. Assertion: The fluorides of alkaline earth metals are relatively less ...

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  12. Assertion: Be is readily attacked by acids. Reason: Be shows diagona...

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  13. Assertion: Alkaline earth metal oxides are quite stable to heat. Rea...

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  14. Assertion: BeSO(4) and MgSO(4) are insoluble in water. Reason: Be^(2...

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