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Bond energy H-H,F-F and H-F bonds are 10...

Bond energy `H-H,F-F and H-F` bonds are 104, 38 and 135 Kcal `"mol"^(-1)`, respectively. The resonance energy in the `H-F` molecule will be

A

142 Kcal `"mol"^(-1)`

B

66 kcal `"mol"^(-1)`

C

`72.14` kcal `"mol"^(-1)`

D

`79.26` kcal `"mol"^(-1)`

Text Solution

Verified by Experts

The correct Answer is:
C

Resonance energy,
`Delta _(H-F)=(BE)_(H-F)- sqrt((BE)_(H_(2))(BeE)_(F_(2)))`
`=135-sqrt(104xx38)`
`=135-62.86=72.14 "kcal mo"^(-1)`
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MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-NATURE OF CHEMICAL BOND -EXERCISE 2 (Miscellaneous Problems)
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  2. If molecule MX3 has zero dipole moment, the sigma bonding orbitals use...

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  3. Which of the following pairs has zero dipole moment ?

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  4. Given : Dipole moment of HCl=1.03 D Bond length of HI=0.38D Bond...

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  5. The correct order of increasing covalent character of the following is

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  6. Bond energy H-H,F-F and H-F bonds are 104, 38 and 135 Kcal "mol"^(-1),...

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  7. Which of the following compounds has the samallest bond angle in its m...

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  8. The bond order of H(2)^(-) ion is (1)/(2). If it has 2 bonding electro...

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  9. Arrange the following molecules in the increasing order of bond angle....

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  10. The compound MX(4) is tetrahedral. The number of angleXMX angles forme...

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  11. Match the following and chose the correct option.

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  12. In XeF(2),XeF(4) and XeF(6)(g) the number of lone pairs on Xe respecti...

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  13. Molecular shapes of SF(4). And CF(4) and XeF(4) are:

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  14. The d-orbitals involved in sp^(3)d hybridisation is:

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  15. In accordance to molecular theory,

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  16. The bond dissociation energy of B-F in BF(3) is 646 kJ mol^(-1) where...

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  17. Which of the following statements (s) is/are true ?

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  18. In which of the following ionixation processes , the bond order has in...

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  19. Consider the following compounds, I, 1,2-hydroxybenzene II 1,3-dih...

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  20. Ortho -nitrophenol is less soluble in water than p-and m-nitrophenols ...

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