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Which of the following reaction is not c...

Which of the following reaction is not correct ?

A

`CH_3undersetoverset(|)(Cl) overset(LiAlH_4)(to) CH_3CH_2CH_3`

B

`(CH_3)_3"CC"l overset(LiAlH_4)(to) (CH_3)_3CH`

C

`(CH_3)_3"CC"l overset(NaBH_4)(to) (CH_3)_3CH`

D

`CH_3l+HI overset(420K)(to) CH_4+I_2`

Text Solution

Verified by Experts

The correct Answer is:
B
`LiAlH_4 " converts " 3^@` alkyl halide into alkene
`(CH_3)_3"CC"l overset(LiAlH_4)(to)(CH_3)_3CH`
Thus, (b) is incorrect .
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MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-ALKANES-EXERCISE 2
  1. The hydrocarbon which is a liquid at room temperature is:

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  2. C8H18 with two quanternary carbon aoms will have

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  3. The correct IUPAC name of the following alkane is

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  4. Following reaction is of the type

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  5. The increasing order of reduction of alkyl halides with zinc and dilut...

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  6. Arrange the halogens F(2),Cl(2),Br(2),I(2), in order of their increasi...

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  7. underset(A)(C5H11Br) underset((ii)D2O)overset((i)Mg//ether)(to)underse...

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  8. A mixture of ethyl iodide and n-propyl iodide is subjected to Wurtz re...

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  9. The reagent used for the conversion CH3CH2COOH to CH3CH2CH3 , is

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  10. Both methane and ethane may be obtained by suitable one step reaction ...

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  11. Arrange the following in decreasing order of their boiling points. (...

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  12. Pure methane can be prepared by

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  13. The highest boiling point is expected for:

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  14. Of the five isomeric hexanes, the isomer which can give two monochlori...

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  15. On mixing certain alkane with chlorine and irradiating it with ultravi...

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  16. Which of the following reaction is not correct ?

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  17. Which of the following alkanes can be easily sulphonated?

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  18. Using C2H5Cl//Na by Wurtz reaction in addition to C4H10, C2H4 " and " ...

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  19. The alkane is not obtained from

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  20. Roversetunderset(||)(O)(C)CH3 (ketone) can be reduced to RCH2CH3 (alka...

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