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A system consisting of 1 mole of an idea...

A system consisting of 1 mole of an ideal gas undergoes an isothermal expansion at `25^(@)` from 1.0 bar to a lower pressure while generating 100 J of work. What is the final pressure of the system if the external pressure of the system is constant of 0.1 bar?

A

1.23 bar

B

0.712 bar

C

0.958 bar

D

0.664 bar

Text Solution

Verified by Experts

The correct Answer is:
B

Given, `p_(ext)=0.1," bar ",R=8.314JK^(-1)mol^(-1),T=298K,`
`p_(1)=1" bar",p_(2)=?`
`W=-p_(ext)(V_(2)-V_(1))`
`=-p_(ext)((nRT)/(p_(2))-(nRT)/(p_(1)))`
`=-nRT" "p_(ext)((1)/(p_(2))-(1)/(p_(1)))`
or `-100=-1xx8.314xx298xx0.1((1)/(p_(2))-(1)/(1))`
`therefore p_(2)=0.712` bar
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MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-CHEMICAL THERMODYNAMICS AND ENERGETIC-MHT CET Corner
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