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For the given reaction, CH(4)(g)+2O(2)...

For the given reaction,
`CH_(4)(g)+2O_(2)(g)toCO_(2)(g)+2H_(2)O(l)`
Select the correct option for `Delta_(r)H`.

A

`[H_(m)(CO_(2),g)+2H_(m)(O_(2),g)]-[2H_(m)(H_(2)O,l)+H_(m)(CH_(4),g)]`

B

`[2H_(m)(O_(2),g)+H_(m)(CH_(4),g)]-[H_(m)(CO_(2),g)+2H_(m)(H_(2)O,l)]`

C

`[H_(m)(CO_(2),g)+2H_(m)(H_(2)O,l)]-[H_(m)(CH_(4),g)+2H_(m)(O_(2),g)]`

D

`[H_(m)(CO_(2),g)+H_(m)(H_(2)O,l)]-[H_(m)(CH_(4),g)+2H_(m)(O_(2),g)]`

Text Solution

Verified by Experts

The correct Answer is:
C

`CH_(4)(g)+2O_(2)(g) to CO_(2)(g)+2H_(2)O(l)`
`Delta_(r)H=underset(i)(sum)sigma_(i)H_("products")-underset(i)(sum)sigma_(i)H_("reactants")`
`=[H_(m)(CO_(2),g)+2H_(m)(H_(2)O,l)]-[H_(m)(CH_(4),g)+2H_(m)(O_(2),g)]`
where, `H_(m)` is the molar enthalpy.
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Calculate the enthalpy change for the following reaction: CH_(4)(g)+2O_(2)(g)toCO_(2)(g)+2H_(2)O(l) given, enthalpies of formation of CH_(4),CO_(2) and H_(2)O are -74.8kJ mol^(-1),-393.5kJ" "mol^(-1) and -286.2kJ" "ml^(-1) respectively.

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MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-CHEMICAL THERMODYNAMICS AND ENERGETIC-Exercise 1
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