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The heat energy required to ionise the f...

The heat energy required to ionise the following molecules is given as follows
`N_(2)(g) overset(DeltaH_(1))to H_(2)^(o+)(g),O_(2)(g) overset(DeltaH_(2))to O_(2)^(+)(g)`
`Li_(2)(g) overset(DeltaH_(3)) to Li_(2)^(o+)(g),C_(2)(g) overset(DeltaH_(4))to C_(2)^(o+)(g)`
The correct decreasing order of energy in terms of heat

A

`DeltaH_(1) gt DeltaH_(3) gt DeltaH_(2) gt DeltaH_(4)`

B

`DeltaH_(2) gt DeltaH_(3) gt DeltaH_(1) gt DeltaH_(4)`

C

`DeltaH_(3) gt DeltaH_(4)gt DeltaH_(1) gt DeltaH_(2)`

D

`DeltaH_(3) gt DeltaH_(1) gt DeltaH_(4) gt DeltaH_(2)`

Text Solution

Verified by Experts

The correct Answer is:
C

Enthalpy of ionisation depends upon the size of molecules. Larger the size lesser will be ionisation energy.
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The heat enegry required to ionise the following molecules is given as follows: N_(2)(g) overset(DeltaH_(1))rarr N_(2)^(o+(g),O_(2)(g) overset(DeltaH_(2))rarrO_(2)^(o+(g) Li_(2)(g) overset(DeltaH_(3))rarrLi_(2)^(o+(g),C_(2)(g) overset(DeltaH_(4))rarrC_(2)^(o+(g) Arrange the heat terms in decreasing order of enegry:

NO(g)to(1)/(2)N_(2)(g)+(1)/(2)O_(2)(g),DeltaH_(1)^(@) 2NO(g)toN_(2)O(g)+(1)/(2)O_(2)(g),DeltaH_(2)^(@) Which relationship is correct ?

Consider the following reaction: (i) O_((g))+e^(-) to O_((g))^(-),DeltaH_(1) (ii) F_((g))+e^(-) to F_((g))^(-),DeltaH_(2) (iii) Cl_((g))+e^(-) to Cl_((g))^(-),DeltaH_(3) (iv) O_((g))^(-) +e^(-) to O_((g))^(2-),DeltaH_(4) then according to given information the correct statement is/are:

Consider the following conversions: (i) O_((g))+e^(-) to O_((g))^(-),DeltaH_(1) (ii) F_((g))+e^(-) to F_((g))^(-),DeltaH_(2) (iii) Cl_((g))+e^(-) to Cl_((g))^(-),DeltaH_(3) (iv) O_((g))^(-) +e^(-) to O_((g))^(2-),DeltaH_(4) the according to given information the incorrect statement is :

MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-CHEMICAL THERMODYNAMICS AND ENERGETIC-Exercise 1
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