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At 1 atm pressure, DeltaS=75JK^(-1)mol^(...

At 1 atm pressure, `DeltaS=75JK^(-1)mol^(-1),DeltaH=30kJ" "mol^(-1)`, the temperature of the reaction at equilibrium is

A

400 K

B

330 K

C

200 K

D

110 K

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The correct Answer is:
To find the temperature of the reaction at equilibrium, we can use the Gibbs free energy equation: \[ \Delta G = \Delta H - T \Delta S \] At equilibrium, \(\Delta G = 0\). Therefore, we can rearrange the equation to find the temperature \(T\): \[ 0 = \Delta H - T \Delta S \] This simplifies to: \[ T \Delta S = \Delta H \] Now, we can solve for \(T\): \[ T = \frac{\Delta H}{\Delta S} \] ### Step 1: Convert \(\Delta H\) to Joules Given: \[ \Delta H = 30 \text{ kJ/mol} = 30,000 \text{ J/mol} \] ### Step 2: Use the given \(\Delta S\) Given: \[ \Delta S = 75 \text{ J/K/mol} \] ### Step 3: Substitute values into the equation for \(T\) Now we can substitute the values into the equation: \[ T = \frac{30,000 \text{ J/mol}}{75 \text{ J/K/mol}} \] ### Step 4: Calculate \(T\) Perform the calculation: \[ T = \frac{30,000}{75} = 400 \text{ K} \] ### Final Answer The temperature of the reaction at equilibrium is \(400 \text{ K}\). ---

To find the temperature of the reaction at equilibrium, we can use the Gibbs free energy equation: \[ \Delta G = \Delta H - T \Delta S \] At equilibrium, \(\Delta G = 0\). Therefore, we can rearrange the equation to find the temperature \(T\): ...
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MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-CHEMICAL THERMODYNAMICS AND ENERGETIC-Exercise 1
  1. The second law of thermodynamics says that in a cyclic process

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  2. Which of the following pairs of a chemical reaction is certain to resu...

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  3. One mole of a perfect gas expands isothermally to ten times of its ori...

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  4. Which of the following does not have zero entropy even at absolute zer...

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  5. In which case, a spontaneous reaction is possible at any temperature

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  6. 2 moles of ann ideal gas at 27^(@)C are expanded reversibly from 2L to...

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  7. At 27^(@)C, latent heat of fusion of a compound is 2930 J/mol. Entropy...

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  8. In evaporation of water, DeltaH and DeltaS are

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  9. Which one of the following is correct?

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  10. The standard free energy change (DeltaG^(@)) is related to equilibrium...

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  11. Find the value of DeltaG^(@) if the DeltaH^(@)=-29.8 kcal and DeltaS^(...

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  12. If K lt 1,0, what will be the value of DeltaG^(@)?

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  13. Find the equilibrium constant K(p) in log K(p) if the standard free en...

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  14. The equilibrium constant for a reaction is 10. what will be the value ...

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  15. Which of the following correctly represents the physical significance ...

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  16. At 1 atm pressure, DeltaS=75JK^(-1)mol^(-1),DeltaH=30kJ" "mol^(-1), th...

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  17. Under which of the following sets of conditions, DeltaG is always nega...

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  18. The gibbs free energy for a reversible reaction at equilibrium is

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  19. Consider the reaction, C(s)+O(2)(g)toCO(2)(g)+393.5kJ, the signs of ...

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  20. The free energy for a reaction having DeltaH=31400cal,DeltaS=32" cal "...

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