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Consider the following reactions: (i) ...

Consider the following reactions:
(i) `(1)/(2)N_(2)(g)+(1)/(2)O_(2)(g) to NO(g),Delta_(r)H^(ө)=90" kJ "mol^(-1)`
(ii) `NO(g)+(1)/(2)O_(2)(g) to NO_(2)(g),Delta_(r)H^(ө)=-74" kJ "mol^(-1)`
Select the correct statement about the given reaction.

A

In (i) reaction, `NO(g)` is unstable because the energy is released. The energy is released in (ii) reaction, `NO_(2)(g)` is stable. Unstable NO(g) changes into the stable `NO_(2)(g)`

B

The energy is absorbed in (i) reaction, NO(g) is unstable. As energy is released in the (ii) reaction `NO_(2)(g)` is stable. That's why unstable NO(g) changes into the stable `NO_(2)(g)`

C

Both (a) and (b)

D

none of these

Text Solution

Verified by Experts

The correct Answer is:
B

In reactionn (i) enerrgy is absorbed hence, NO becomes unstable so in reaction (ii) it transform to `NO_(2)` by releasing energy.
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MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-CHEMICAL THERMODYNAMICS AND ENERGETIC-Exercise 2
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  5. In an irreversible process taking place at constant T and p and in whi...

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  6. In adiabatic conditions 1 mole of CO(2) gas at 300 K is expanded such ...

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  8. 1.0 mole of a monoatomic ideal gas is expanded from state (I) to state...

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  9. What is the equilibrium constant, K for the following reaction at 400 ...

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  10. Match the columns with the laws of thermodynamics.

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  11. Match the columns with the atomicity of gases to the heat capacity at ...

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  13. A sample of 1.0 mole of a monoatomic ideal gas is taken through a proc...

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  14. What would be the heat released when an aqueous solution containing 0....

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  15. The molar heat capacity of water at constant pressure is 75 JK^(-1)mol...

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  16. For a reaction at 25^(@)C, enthalpy and entropy changes are -11.7xx10^...

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  17. The standard molar heat of formation ethane, CO(2) and water (l) are r...

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  18. The DeltaH(f)^(@) of O(3),CO(3),NH(3) and HI are 142.2, -393.3, -46.2 ...

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  19. One molee of methanol when burnt in O(2), gives out 723 kJ mol^(-1) of...

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  20. DeltaH(f)^@ (298K) of methanol is given by the chemical equation,

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